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Probing molecule–surface interactions through ultra-fast adsorbate dynamics: propane/Pt(111)

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Published 22 December 2008 Published under licence by IOP Publishing Ltd
, , Focus on Advances in Surface and Interface Science 2008 Citation A P Jardine et al 2008 New J. Phys. 10 125026 DOI 10.1088/1367-2630/10/12/125026

1367-2630/10/12/125026

Abstract

3He spin echo measurements of the atomic scale motion of propane on a Pt(111) surface are presented. The measurements provide both the height of the energy barriers to diffusion and the strength of the frictional coupling of propane to the substrate. We show that both the rate and the nature of the dynamics we measure cannot be reproduced by an existing empirical potential. Using numerical simulation we derive a potential energy surface which is capable of reproducing the main features of our dataset.

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10.1088/1367-2630/10/12/125026