Journal Description
Materials
Materials
is an international peer-reviewed, open access journal on materials science and engineering published semimonthly online by MDPI. The Portuguese Materials Society (SPM), Spanish Materials Society (SOCIEMAT) and Manufacturing Engineering Society (MES) are affiliated with Materials and their members receive discounts on the article processing charges.
- Open Access— free for readers, with article processing charges (APC) paid by authors or their institutions.
- High Visibility: indexed within Scopus, SCIE (Web of Science), PubMed, PMC, Ei Compendex, CaPlus / SciFinder, Inspec, Astrophysics Data System, and other databases.
- Journal Rank: JCR - Q2 (Metallurgy & Metallurgical Engineering) / CiteScore - Q2 (Condensed Matter Physics)
- Rapid Publication: manuscripts are peer-reviewed and a first decision is provided to authors approximately 13.9 days after submission; acceptance to publication is undertaken in 2.7 days (median values for papers published in this journal in the second half of 2023).
- Recognition of Reviewers: reviewers who provide timely, thorough peer-review reports receive vouchers entitling them to a discount on the APC of their next publication in any MDPI journal, in appreciation of the work done.
- Testimonials: See what our editors and authors say about Materials.
- Companion journals for Materials include: Electronic Materials and Construction Materials.
Impact Factor:
3.4 (2022);
5-Year Impact Factor:
3.8 (2022)
Latest Articles
Investigation of the Penetration Performance of the Radial Forging Process for Wrought Aluminium Alloy
Materials 2024, 17(9), 2065; https://doi.org/10.3390/ma17092065 (registering DOI) - 27 Apr 2024
Abstract
With the wide application potential of wrought aluminium alloy in aerospace, automobile and electronic products, high-quality aluminium bars prepared by the radial forging (RF) process have received extensive attention. Penetration performance refers to the depth of radial plastic deformation of forgings, which is
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With the wide application potential of wrought aluminium alloy in aerospace, automobile and electronic products, high-quality aluminium bars prepared by the radial forging (RF) process have received extensive attention. Penetration performance refers to the depth of radial plastic deformation of forgings, which is the key factor in determining the quality of forging. In this work, the penetration performance of the radial forging process for 6063 wrought aluminium bars is investigated by simulation using FORGE software. The minimum reduction amount of the hammer is calculated based on the forging penetration theory of forging. The influence of process parameters including forging ratio (FR) and billet temperature on the effective stress and hammer load in the RF process are investigated. The RF-deformed billet is then produced with the optimal process parameters obtained from the simulation results. The average grain size of aluminium alloy semi-solid spherical material is used to evaluate the forging penetration. Simulation results showed that the effective strain at the edge and the centre of the RF-deformed billet gradually increases, but the increasing speed of the effective strain at the edge becomes low. The hammer load first decreases quickly and then gradually maintains stability by increasing the FR. It is found that low billet temperature and high FR should be selected as appropriate process parameters under the allowable tonnage range of RF equipment. Under an isothermal temperature of 630 °C and a sustaining time of 10 min, the difference in the average grain dimension between the edge and the centre positions of the starting extruded blank is 186.43 μm, while the difference in the average grain dimension between the edge and the centre positions of the RF-deformed blank is 15.09 μm. The improvement ratio of penetration performance for the RF-deformed blank is obtained as 91.19%.
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(This article belongs to the Special Issue Mechanical Performance and Microstructural Characterization of Light Alloys (Volume II))
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Open AccessArticle
Methodology of Chip Temperature Measurement and Safety Machining Assessment in Dry Rough Milling of Magnesium Alloys Using Different Helix Angle Tools
by
Ireneusz Zagórski, Piotr Zgórniak, Witold Habrat, José Machado and Stanisław Legutko
Materials 2024, 17(9), 2063; https://doi.org/10.3390/ma17092063 (registering DOI) - 27 Apr 2024
Abstract
This paper presents the methodology of measuring chip temperature in the cutting zone in the rough milling of magnesium alloys. Infrared measurements are taken to determine the effect of variable cutting speed, feed per tooth, and depth of cut on the maximum temperature
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This paper presents the methodology of measuring chip temperature in the cutting zone in the rough milling of magnesium alloys. Infrared measurements are taken to determine the effect of variable cutting speed, feed per tooth, and depth of cut on the maximum temperature of chips. Thermal images of chip temperature for a generated collective frame and corresponding histograms are presented. Chip temperatures are presented in numerical terms as median and average values; maximum and minimum values; range; and standard deviation. Box plots are also shown for selected machining conditions. The problems arising during signal recording with a mean emissivity coefficient ε = 0.13, a value which is dedicated during machining magnesium alloys, are discussed in detail. Chip temperatures obtained in the tests do not exceed approx. 420 °C. Therefore, the dry rough milling process carried out with carbide tools with different blade geometries can be considered safe for a wide range of machining parameters. The proposed methodology of chip temperature measurement and result processing is a new and effective approach to safety assessment in the dry milling of magnesium alloys.
Full article
(This article belongs to the Section Manufacturing Processes and Systems)
Open AccessArticle
First-Principles Study of Adsorption of CH4 on a Fluorinated Model NiF2 Surface
by
Tilen Lindič and Beate Paulus
Materials 2024, 17(9), 2062; https://doi.org/10.3390/ma17092062 (registering DOI) - 27 Apr 2024
Abstract
Electrochemical fluorination on nickel anodes, also known as the Simons’ process, is an important fluorination method used on an industrial scale. Despite its success, the mechanism is still under debate. One of the proposed mechanisms involves higher valent nickel species formed on an
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Electrochemical fluorination on nickel anodes, also known as the Simons’ process, is an important fluorination method used on an industrial scale. Despite its success, the mechanism is still under debate. One of the proposed mechanisms involves higher valent nickel species formed on an anode acting as effective fluorinating agents. Here we report the first attempt to study fluorination by means of first principles investigation. We have identified a possible surface model from the simplest binary nickel fluoride (NiF2). A twice oxidized NiF2(F2) (001) surface exhibits higher valent nickel centers and a fluorination source that can be best characterized as an [F2]- like unit, readily available to aid fluorination. We have studied the adsorption of CH4 and the co-adsorption of CH4 and HF on this surface by means of periodic density functional theory. By the adsorption of CH4, we found two main outcomes on the surface. Unreactive physisorption of CH4 and dissociative chemisorption resulting in the formation of CH3F and HF. The co-adsorption with the HF gave rise to four main outcomes, namely the formation of CH3F, CH2F2, CH3 radical, and also physisorbed CH4.
Full article
(This article belongs to the Special Issue The 15th Anniversary of Materials—Recent Advances in Catalytic Materials)
Open AccessArticle
The Effect of Laser Remelting during SLM on Microstructure and Mechanical Properties of CoCrFeNiNb0.25
by
Zhiyuan Yang, Chan Guo, Tao Sun, Jinpeng Hu, Xiaomei Feng and Yifu Shen
Materials 2024, 17(9), 2061; https://doi.org/10.3390/ma17092061 (registering DOI) - 27 Apr 2024
Abstract
A sub-eutectic high-entropy alloy composed of CoCrFeNiNb0.25 was prepared using a combination of mechanical powder mixing and selective laser melting (SLM). The mechanical properties of the alloy were enhanced by employing an interlayer laser remelting process. This study demonstrates the feasibility of
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A sub-eutectic high-entropy alloy composed of CoCrFeNiNb0.25 was prepared using a combination of mechanical powder mixing and selective laser melting (SLM). The mechanical properties of the alloy were enhanced by employing an interlayer laser remelting process. This study demonstrates the feasibility of using mechanical mixing and SLM to form an CoCrFeNiNb0.25 alloy. The interlayer laser remelting process can effectively promote the melting of Nb particles introduced by mechanical mixing, release the stresses near the unfused Nb particles, and reduce their degradation of the specimen properties. The results indicate that the CoCrFeNiNb0.25 alloy, prepared using the interlayer laser remelting process, had an average microhardness of 376 HV, a tensile strength of 974 MPa, and an elongation at break of 10.51%. This process offers a viable approach for rapidly adjusting the composition of high-entropy alloys for SLM forming.
Full article
Open AccessArticle
Influence of Pulsed Interference Laser Heating on Crystallisation of Amorphous Fe77Cu1Si13B9 Ribbons
by
Agnieszka Radziszewska and Olaf Czyż
Materials 2024, 17(9), 2060; https://doi.org/10.3390/ma17092060 (registering DOI) - 27 Apr 2024
Abstract
Amorphous Fe77Cu1Si13B9 ribbons were treated with pulsed laser interference heating (PLIH). The research results will significantly contribute to a better understanding of the impact of PLIH on crystallisation and magnetic properties in precisely defined micro-areas of
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Amorphous Fe77Cu1Si13B9 ribbons were treated with pulsed laser interference heating (PLIH). The research results will significantly contribute to a better understanding of the impact of PLIH on crystallisation and magnetic properties in precisely defined micro-areas of Fe77Cu1Si13B9 (FeCuSiB) ribbons, which has not yet been described in the literature. It was confirmed here that the use of the laser heating process allowed for the achievement of two-dimensional crystallised micro-areas, periodically distributed (at a distance of 17 µm) on the surface of the amorphous ribbons. The correlation between structural changes (SEM, TEM, HRTEM) and the distribution of magnetic field lines of heated amorphous Fe77Cu1Si13B9 ribbons is presented. Particular attention is paid to structural changes in micro-areas where, by controlling the laser interference heating process, the partial crystallisation of amorphous alloys and the formation of clusters or single nanocrystallites (α-Fe(Si)) embedded in an amorphous matrix occur. The addition of copper to the FeSiB alloy promoted the inhibition of grain growth. Electron holography of micro-areas confirmed shifts in the magnetic field lines in the areas of nanocrystallites, the presence of which in the structure caused the magnetisation of the surrounding amorphous matrix.
Full article
(This article belongs to the Section Metals and Alloys)
Open AccessTechnical Note
Exploring the Potential of a Novel Iodine-Based Material as an Alternative Contrast Agent in X-ray Imaging Studies
by
Kristina Bliznakova, Iliyan Kolev, Nikolay Dukov, Tanya Dimova and Zhivko Bliznakov
Materials 2024, 17(9), 2059; https://doi.org/10.3390/ma17092059 (registering DOI) - 27 Apr 2024
Abstract
Background: Contrast-enhanced mammography is one of the new emerging imaging techniques used for detecting breast tissue lesions. Optimization of imaging protocols and reconstruction techniques for this modality, however, requires the involvement of physical phantoms. Their development is related to the use of radiocontrast
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Background: Contrast-enhanced mammography is one of the new emerging imaging techniques used for detecting breast tissue lesions. Optimization of imaging protocols and reconstruction techniques for this modality, however, requires the involvement of physical phantoms. Their development is related to the use of radiocontrast agents. This study assesses the X-ray properties of a novel contrast material in clinical settings. This material is intended for experimental use with physical phantoms, offering an alternative to commonly available radiocontrast agents. Materials and Methods: The water-soluble sodium salt of the newly synthesized diiodine-substituted natural eudesmic acid, Sodium 2,6-DiIodo-3,4,5-TriMethoxyBenzoate [NaDITMB], has been investigated with respect to one of the most commonly applied radiocontrast medium in medical practice—Omnipaque®. For this purpose, simulation and experimental studies were carried out with a computational phantom and a physical counterpart, respectively. Synthetic and experimental X-ray images were subsequently produced under varying beam kilovoltage peaks (kVps), and the proposed contrast material was evaluated. Results and Discussion: Simulation results revealed equivalent absorptions between the two simulated radiocontrast agents. Experimental findings supported these simulations, showing a maximum deviation of 3.7% between the image gray values of contrast materials for NaDITMB and Omnipaque solutions for a 46 kVp X-ray beam. Higher kVp X-ray beams show even smaller deviations in the mean grey values of the imaged contrast agents, with the NaDITMB solution demonstrating less than a 2% deviation compared to Omnipaque. Conclusion: The proposed contrast agent is a suitable candidate for use in experimental work related to contrast-enhanced imaging by utilizing phantoms. It boasts the advantages of easy synthesis and is recognized for its safety, ensuring a secure environment for both the experimenter and the environment.
Full article
(This article belongs to the Special Issue Advanced Biomaterials for Medical Applications (2nd Edition))
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Open AccessEditorial
Characterization, Applications and New Technologies of Civil Engineering Materials and Structures
by
Wensheng Wang, Qinglin Guo and Jue Li
Materials 2024, 17(9), 2058; https://doi.org/10.3390/ma17092058 (registering DOI) - 27 Apr 2024
Abstract
With the continuous development of large-scale maintenance of infrastructure, accurate, reasonable, and efficient mechanical behavior evaluation and performance prediction of civil materials and structures have become the keys to improving service durability and intelligent maintenance management for infrastructure [...]
Full article
(This article belongs to the Special Issue Characterization, Applications and New Technologies of Civil Engineering Materials and Structures)
Open AccessReview
A State of the Art on Cryogenic Cooling and Its Applications in the Machining of Difficult-to-Machine Alloys
by
Mehmet Erdi Korkmaz and Munish Kumar Gupta
Materials 2024, 17(9), 2057; https://doi.org/10.3390/ma17092057 (registering DOI) - 27 Apr 2024
Abstract
Cryogenic cooling has gathered significant attention in the manufacturing industry. There are inherent difficulties in machining materials that are difficult to machine because of high levels of hardness, abrasiveness, and heat conductivity. Increased tool wear, diminished surface finish, and reduced machining efficiency are
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Cryogenic cooling has gathered significant attention in the manufacturing industry. There are inherent difficulties in machining materials that are difficult to machine because of high levels of hardness, abrasiveness, and heat conductivity. Increased tool wear, diminished surface finish, and reduced machining efficiency are the results of these problems, and traditional cooling solutions are insufficient to resolve them. The application of cryogenic cooling involves the use of extremely low temperatures, typically achieved by employing liquid nitrogen or other cryogenic fluids. This study reviews the current state of cryogenic cooling technology and its use in machining difficult-to-machine materials. In addition, this review encompasses a thorough examination of cryogenic cooling techniques, including their principles, mechanisms, and effects on machining performance. The recent literature was used to discuss difficult-to-machine materials and their machining properties. The role of cryogenic cooling in machining difficult materials was then discussed. Finally, the latest technologies and methods involved in cryogenic cooling condition were discussed in detail. The outcome demonstrated that the exploration of cryogenic cooling methods has gained prominence in the manufacturing industry due to their potential to address challenges associated with the machining of exotic alloys.
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(This article belongs to the Special Issue Advanced Machining Technology for Modern Engineering Materials (2nd Edition))
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Open AccessArticle
Investigation of Microstructure and Mechanical Properties of High-Depth-to-Width-Ratio Horizontal NG-GMAW Joint for S500Q Steel
by
Ruiyan Jia, Haichao Li, Fangkai Wei, Yufei Zhou, Weizan Duan, Kuiliang Zhang and Zhenglong Lei
Materials 2024, 17(9), 2056; https://doi.org/10.3390/ma17092056 (registering DOI) - 27 Apr 2024
Abstract
A novel high depth-to-width ratio of 15:1 narrow-gap gas metal arc welding technique was developed for the welding of S500Q steel in a horizontal butt joint. The bead arrangement of the I groove was optimized to produce a high-quality connection with the upper
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A novel high depth-to-width ratio of 15:1 narrow-gap gas metal arc welding technique was developed for the welding of S500Q steel in a horizontal butt joint. The bead arrangement of the I groove was optimized to produce a high-quality connection with the upper sidewall of the joint. The microstructure and mechanical properties were observed and evaluated by optical microscopy, scanning electron microscopy, tensile testing, and micro-hardness and impact toughness testing at 1/5, 2/5, 3/5, and 4/5 thickness of the joint. The 3/5 T position exhibited the highest strength, which was attributed to the presence of finer carbide precipitates. The highest micro-hardness appeared at 4/5 T. The highest impact toughness appeared at 3/5 T. The formation of coarse granular bainite was the major reason for the decrease in impact toughness in other regions. A microscopic fracture at 1/5 T and 3/5 T was further analyzed. It was observed that the width of the fibrous zone at 3/5 T was significantly larger than that at 1/5 T. The radial zones at 1/5 T were observed to exhibit cleavage, with secondary cracks on the fracture surface.
Full article
(This article belongs to the Special Issue Advances in the Welding of Materials)
Open AccessArticle
On the Fundamentals of Reverse Ring Rolling: A Numerical Proof of Concept
by
Ioannis S. Pressas, Spyros Papaefthymiou and Dimitrios E. Manolakos
Materials 2024, 17(9), 2055; https://doi.org/10.3390/ma17092055 (registering DOI) - 27 Apr 2024
Abstract
Ring Rolling is a near-net manufacturing process with some measurable dimensional inaccuracies in its products. This fact is exaggerated even more under the scope of high-precision manufacturing, where these imprecisions render such products unfitting for the strict dimensional requirements of high-precision applications (e.g.,
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Ring Rolling is a near-net manufacturing process with some measurable dimensional inaccuracies in its products. This fact is exaggerated even more under the scope of high-precision manufacturing, where these imprecisions render such products unfitting for the strict dimensional requirements of high-precision applications (e.g., bearings, casings for turbojets, etc.). In order to remedy some of the dimensional inaccuracies of Ring Rolling, the novel approach of Reverse Ring Rolling is proposed and investigated in the current analysis. The conducted research was based on a numerical simulation of a flat Ring Rolling process, previously presented by the authors. Since the final dimensions of the ring from the authors’ previous work diverged from those initially expected, the simulation of a subsequent Reverse Ring Rolling process was performed to reach the target dimensions. The calculated deformational results revealed a great agreement in at least two of the three crucial dimensions. Additionally, the evaluation of the calculated stress, strain, temperature and load results revealed key aspects of the mechanisms that occur during the proposed process. Overall, it was concluded that Reverse Ring Rolling can effectively function as a corrective process, which can increase the dimensional accuracy of a seamless ring product with little additional post-processing and cost.
Full article
(This article belongs to the Special Issue Advanced Computational Methods in Manufacturing Processes)
Open AccessArticle
Decomposition Kinetics and Lifetime Estimation of Thermoplastic Composite Materials Reinforced with rCFRP
by
Juana Abenojar, Gladis Miriam Aparicio, José Antonio Butenegro, Mohsen Bahrami and Miguel Angel Martínez
Materials 2024, 17(9), 2054; https://doi.org/10.3390/ma17092054 (registering DOI) - 27 Apr 2024
Abstract
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Because of the high demand for carbon fiber reinforced polymer (CFRP) materials across all industries, the reuse and/or recycling of these materials (rCFRP) is necessary in order to meet the principles of the circular economy, including recycling and reuse. The objective of this
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Because of the high demand for carbon fiber reinforced polymer (CFRP) materials across all industries, the reuse and/or recycling of these materials (rCFRP) is necessary in order to meet the principles of the circular economy, including recycling and reuse. The objective of this study is to estimate the lifespan of thermoplastic matrix composite materials reinforced with waste materials (CFRP), which undergo only a mechanical cutting process. This estimation is carried out through the thermal decomposition of polymers, including polymer matrix composite materials, which is a complex process due to the numerous reactions involved. Some authors calculate these kinetic parameters using thermogravimetric analysis (TGA) as it is a quick method, and it allows the identification of gases released during decomposition, provided that the equipment is prepared for it. This study includes a comparison between polyamides 11 and 12, as well as between polyamide composite materials with carbon fiber (CF) and polyamides reinforced with CF/epoxy composite material. The latter is treated with plasma to improve adhesion with polyamides. The behavior of weight as a function of temperature was studied at speeds of 3, 6, 10, 13, 17, and 20 °C/min, finding stability of the polyamides up to a temperature of 400 °C, which was consistent with the analysis by mass spectroscopy, where gas evolution is evident after 400 °C. The estimation of the lifespan was carried out using two different methods including the Toop equation and the free kinetics model (MFK). The energy of the decomposition process was determined using the MFK model, which establishes the energy as a function of the degree of conversion. It is estimated that at 5% decomposition, mechanical properties are lost.
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Open AccessArticle
Study on the Effect of Citric Acid-Modified Chitosan on the Mechanical Properties, Shrinkage Properties, and Durability of Concrete
by
Zhibin Qin, Jiandong Wu, Zhenhao Hei, Liguo Wang, Dongyi Lei, Kai Liu and Ying Li
Materials 2024, 17(9), 2053; https://doi.org/10.3390/ma17092053 (registering DOI) - 27 Apr 2024
Abstract
As an environmentally friendly natural polymer, citric acid-modified chitosan (CAMC) can effectively regulate the hydration and exothermic processes of cement-based materials. However, the influence of CAMC on the macroscopic properties of concrete and the optimal dosage are still unclear. This work systematically investigates
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As an environmentally friendly natural polymer, citric acid-modified chitosan (CAMC) can effectively regulate the hydration and exothermic processes of cement-based materials. However, the influence of CAMC on the macroscopic properties of concrete and the optimal dosage are still unclear. This work systematically investigates the effects of CAMC on the mixing performance, mechanical properties, shrinkage performance, and durability of concrete. The results indicated that CAMC has a thickening effect and prolongs the setting time of concrete. CAMC has a negative impact on the early strength of concrete, but it is beneficial for the development of the subsequent strength of concrete. With the increase in CAMC content, the self-shrinkage rate of concrete samples decreased from 86.82 to 14.52 με. However, the CAMC-0.6% sample eventually expanded, with an expansion value of 78.49 με. Moreover, the long-term drying shrinkage rate was decreased from 551.46 to 401.94 με. Furthermore, low-dose CAMC can significantly reduce the diffusion coefficient of chloride ions, improve the impermeability and density of concrete, and thereby enhance the freeze–thaw cycle resistance of concrete.
Full article
(This article belongs to the Special Issue Microstructure, Characteristics, and Failure Behaviors of Cementitious Composites)
Open AccessArticle
Controlled Size Characterization Process for In-Situ TiB2 Particles from Al Matrix Composites Using Nanoparticle Size Analysis
by
Mingliang Wang, Qian Wang, Zeyu Bian, Siyi Chen, Yue Gong, Cunjuan Xia, Dong Chen and Haowei Wang
Materials 2024, 17(9), 2052; https://doi.org/10.3390/ma17092052 (registering DOI) - 27 Apr 2024
Abstract
The wide size range and high tendency to agglomerate of in-situ TiB2 particles in reinforced Al matrix composites introduce great difficulties in their size characterization. In order to use a nanoparticle size analyzer (NSA) to obtain the precise size distribution of TiB
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The wide size range and high tendency to agglomerate of in-situ TiB2 particles in reinforced Al matrix composites introduce great difficulties in their size characterization. In order to use a nanoparticle size analyzer (NSA) to obtain the precise size distribution of TiB2 particles, a controlled size characterization process has been explored. First, the extraction and drying processes for TiB2 particles were optimized. In the extraction process, alternated applications of magnetic stirring and normal ultrasound treatments were proven to accelerate the dissolution of the Al matrix in HCl solution. Furthermore, freeze-drying was found to minimize the agglomeration tendency among TiB2 particles, facilitating the acquisition of pure powders. Such powders were quantitatively made into an initial TiB2 suspension. Second, the chemical and physical dispersion technologies involved in initial TiB2 suspension were put into focus. Chemically, adding PEI (M.W. 10000) at a ratio of mPEI/mTiB2 = 1/30 into the initial suspension can greatly improve the degree of TiB2 dispersion. Physically, the optimum duration for high-energy ultrasound application to achieve TiB2 dispersion was 10 min. Overall, the corresponding underlying dispersion mechanisms were discussed in detail. With the combination of these chemical and physical dispersion specifications for TiB2 suspension, the bimodal size distribution of TiB2 was able to be characterized by NSA for the first time, and its number-average diameter was 111 ± 6 nm, which was reduced by 59.8% over the initial suspension. Indeed, the small-sized and large-sized peaks of the TiB2 particles characterized by NSA mostly match the results obtained from transmission electron microscopy and scanning electron microscopy, respectively.
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(This article belongs to the Special Issue Advances in Light Alloys and Related Composites)
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Comparison of the Mechanical Properties of Hardfacings Made by Standard Coated Stick Electrodes and a Newly Developed Rectangular Stick Electrode
by
Edvard Bjelajac, Andrej Skumavc, Gorazd Lojen, Mirza Manjgo and Tomaž Vuherer
Materials 2024, 17(9), 2051; https://doi.org/10.3390/ma17092051 (registering DOI) - 27 Apr 2024
Abstract
Cladding with a stick electrode is one of the oldest arc processes for adding a deposit on a base material. The process is suitable for outdoor working, but the disadvantages are low productivity and large dilution rates. In this work, a simple solution
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Cladding with a stick electrode is one of the oldest arc processes for adding a deposit on a base material. The process is suitable for outdoor working, but the disadvantages are low productivity and large dilution rates. In this work, a simple solution is proposed, which would enable cladding of a larger area with one pass and decrease the dilution rate at the same time—a new type of electrode was developed, exhibiting a rectangular cross-section instead of a round one.: Hardfacings, welded with E Fe8 electrodes according to EN 14 700 Standard were welded on mild steel S355 J2 base material with three different coated stick electrodes. The first one was a commercially available, standard, round hardfacing electrode, the second was the same, but with a thinner coating, and the third one was a newly developed rectangular electrode. All three types had equal cross-sections of the metallic core and the same type of coating. Manufacturing of the rectangular electrodes in the laboratory is explained briefly. One- and multi-layer deposits were welded with all three types. Differences were observed in the arc behavior between the round and rectangular electrodes. With the rectangular electrode, the microstructure of the deposit was finer, penetration was shallower, and dilution rates were lower, while the hardness was higher, residual stresses predominantly compressive, and the results of instrumented Charpy impact tests and fracture mechanics tests were better.
Full article
(This article belongs to the Special Issue Welding, Joining, and Additive Manufacturing of Metals and Alloys)
Open AccessArticle
Research Enhancing Acidic Mine Wastewater Purification: Innovations in Red Mud–Loess
by
Wdah. T. Salih, Zean Xiao and Xiaoqiang Dong
Materials 2024, 17(9), 2050; https://doi.org/10.3390/ma17092050 (registering DOI) - 26 Apr 2024
Abstract
This study investigates the adsorption of cadmium (Cd) by red mud–loess mixed materials and assesses the influence of quartz sand content on permeability. Shear tests are conducted using various pore solutions to analyze shear strength parameters. The research validates solidification methods for cadmium-contaminated
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This study investigates the adsorption of cadmium (Cd) by red mud–loess mixed materials and assesses the influence of quartz sand content on permeability. Shear tests are conducted using various pore solutions to analyze shear strength parameters. The research validates solidification methods for cadmium-contaminated soils and utilizes SEM-EDS, FTIR, and XRD analysis to elucidate remediation mechanisms. The findings suggest that the quartz sand content crucially affects the permeability of fine-grained red mud–loess mixtures. The optimal proportion of quartz sand is over 80%, significantly enhancing permeability, reaching a coefficient of 6.7 × 10−4 cm/s. Insufficient quartz sand content of less than 80% fails to meet the barrier permeability standards, leading to a reduced service life of the engineered barrier. Adsorption tests were conducted using various pore solutions, including distilled water, acidic solutions, and solutions containing Cd, to evaluate the adsorption capacity and shear characteristics of the red mud–loess mixture. Additionally, the study examines the behavior of Cd-loaded red mud–loess mixtures in various pore solutions, revealing strain-hardening trends and alterations in cohesiveness and internal friction angle with increasing Cd concentrations. The analysis of cement–red mud–loess-solidified soil demonstrates enhancements in soil structure and strength over time, attributed to the formation of crystalline structures and mineral formations induced by the curing agent. These findings provide valuable insights into the remediation of cadmium-contaminated soils.
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Open AccessArticle
Profile Optimisation of a Solid Modular Hob in the Machining of Gears Made of Classic and Unusual, Innovative Materials
by
Andrzej Piotrowski and Artur Tyliszczak
Materials 2024, 17(9), 2049; https://doi.org/10.3390/ma17092049 (registering DOI) - 26 Apr 2024
Abstract
Modular hobs are tools with very complex geometry. Regardless of the material of the gear wheels, they determine the accuracy of the gears made in the hobbing machining process. Gears are made of various, often innovative materials depending on the requirements. Sometimes, the
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Modular hobs are tools with very complex geometry. Regardless of the material of the gear wheels, they determine the accuracy of the gears made in the hobbing machining process. Gears are made of various, often innovative materials depending on the requirements. Sometimes, the materials are characterised by very high hardness (over 65 HRC). The mathematical basis for describing the faces of a hob presented in the article allows for modifying the rack profile shaping the gear wheel’s teeth. The model’s universality makes it possible to perform numerical simulations of the influence of individual parameters of the hob creation process (geometry of the grinding wheels and their setting in the shaping process) on the profile of the rake and flank surfaces. The cutting edge (rack edge) is the locus of points belonging to both of these surfaces and thus directly impacts the accuracy of the gear wheel that is shaped in the hobbing process. The article summarises the authors’ long-term cooperation with the industry, resulting in a series of articles devoted to hobs. The issues presented in the article are significant to the machinery industry and hob manufacturers.
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(This article belongs to the Special Issue Modelling, Simulation and Optimisation of Non-typical and Innovative Materials)
Open AccessArticle
The Use of Wind Turbine Blades to Build Road Noise Barriers as an Example of a Circular Economy Model
by
Mirosław Broniewicz, Anna Halicka, Lidia Buda-Ożóg, Filip Broniewicz, Damian Nykiel and Łukasz Jabłoński
Materials 2024, 17(9), 2048; https://doi.org/10.3390/ma17092048 - 26 Apr 2024
Abstract
This project’s objective was to create a circular economy in the composites sector by examining the possibility of using wind turbine blade composite materials to construct noise-absorbing barriers for roads. The possibility of constructing road noise barrier panels from components obtained from turbine
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This project’s objective was to create a circular economy in the composites sector by examining the possibility of using wind turbine blade composite materials to construct noise-absorbing barriers for roads. The possibility of constructing road noise barrier panels from components obtained from turbine blades was conceptually examined, and the geometry and construction of wind turbine blades were evaluated for their suitability as filler components for panels. The tensile strength parameters of two types of composites made from windmill blades—a solid composite and a sandwich type—were established based on material tests. The strength of the composite elements cut from a windmill propeller was analyzed, and a three-dimensional numerical model was created using the finite element method. The strength values of the composite used to construct the noise barriers were compared with the stresses resulting from loads operating on the road noise barriers, as determined in compliance with current standards. It was discovered that acoustic screens composed of composite materials derived from wind turbine blades may withstand loads associated with wind pressure and vehicle traffic with sufficient resistance. In order to evaluate the environmental benefits resulting from the use of composite material made from wind turbine blades to make noise barriers, this study presents the values of the embodied energy and embodied carbon for several types of road noise barriers using life cycle assessment.
Full article
(This article belongs to the Special Issue Manufacturing of Porous Acoustic Structures and Metamaterials)
Open AccessArticle
Design and In Vitro Activity of Furcellaran/Chitosan Multilayer Microcapsules for the Delivery of Glutathione and Empty Model Multilayer Microcapsules Based on Polysaccharides
by
Mariola Drozdowska, Ewelina Piasna-Słupecka, Aleksandra Such, Kinga Dziadek, Paweł Krzyściak, Tomasz Kruk, Dorota Duraczyńska, Małgorzata Morawska-Tota and Ewelina Jamróz
Materials 2024, 17(9), 2047; https://doi.org/10.3390/ma17092047 - 26 Apr 2024
Abstract
In this study, multilayer microcapsules (two-layer and four-layer) based on furcellaran (FUR) and chitosan (CHIT) were produced, enclosing a tripeptide with an antioxidant effect—glutathione—in different concentrations. In addition, for the first time, an empty, four-layer microcapsule based on CHIT and FUR (ECAPS) was
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In this study, multilayer microcapsules (two-layer and four-layer) based on furcellaran (FUR) and chitosan (CHIT) were produced, enclosing a tripeptide with an antioxidant effect—glutathione—in different concentrations. In addition, for the first time, an empty, four-layer microcapsule based on CHIT and FUR (ECAPS) was obtained, which can be used to contain sensitive, active substances of a hydrophobic nature. Layering was monitored using zeta potential, and the presence of the resulting capsules was confirmed by SEM imaging. In the current study, we also investigated whether the studied capsules had any effect on the Hep G2 cancer cell line. An attempt was also made to identify the possible molecular mechanism(s) by which the examined capsules suppressed the growth of Hep G2 cells. In this report, we demonstrate that the capsules suppressed the growth of cancer cells. This mechanism was linked to the modulation of the AKT/PI3K signaling pathway and the induction of the G2/M arrest cell cycle. Furthermore, the results indicate that the tested multilayer microcapsules induced cell death through an apoptotic pathway.
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Open AccessArticle
Controlling the Size of Hydrotalcite Particles and Its Impact on the Thermal Insulation Capabilities of Coatings
by
Yanhua Zhao, Guanhua Shen, Yongli Wang, Xiangying Hao and Huining Li
Materials 2024, 17(9), 2046; https://doi.org/10.3390/ma17092046 - 26 Apr 2024
Abstract
This study focuses on the development of high-performance insulation materials to address the critical issue of reducing building energy consumption. Magnesium–aluminum layered double hydroxides (LDHs), known for their distinctive layered structure featuring positively charged brucite-like layers and an interlayer space, have been identified
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This study focuses on the development of high-performance insulation materials to address the critical issue of reducing building energy consumption. Magnesium–aluminum layered double hydroxides (LDHs), known for their distinctive layered structure featuring positively charged brucite-like layers and an interlayer space, have been identified as promising candidates for insulation applications. Building upon previous research, which demonstrated the enhanced thermal insulation properties of methyl trimethoxysilane (MTS) functionalized LDHs synthesized through a one-step in situ hydrothermal method, this work delves into the systematic exploration of particle size regulation and its consequential effects on the thermal insulation performance of coatings. Our findings indicate a direct correlation between the dosage of MTS and the particle size of LDHs, with an optimal dosage of 4 wt% MTS yielding LDHs that exhibit a tightly interconnected hydrotalcite lamellar structure. This specific modification resulted in the most significant improvement in thermal insulation, achieving a temperature difference of approximately 25.5 °C. Furthermore, to gain a deeper understanding of the thermal insulation mechanism of MTS-modified LDHs, we conducted a thorough characterization of their UV-visible diffuse reflectance and thermal conductivity. This research contributes to the advancement of LDH-based materials for use in thermal insulation applications, offering a sustainable solution to energy conservation in the built environment.
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(This article belongs to the Special Issue Polymer Surface Modification and Characterization)
Open AccessArticle
The Influence of Thickness on Light Transmission for Pre- and Fully Crystallized Chairside CAD/CAM Lithium Disilicate Ceramics
by
Franciele Floriani, Salahaldeen Abuhammoud, Silvia Rojas-Rueda, Amit Unnadkat, Nicholas G. Fischer, Chin-Chuan Fu and Carlos A. Jurado
Materials 2024, 17(9), 2045; https://doi.org/10.3390/ma17092045 - 26 Apr 2024
Abstract
Aim: This in vitro study aimed to compare the light-transmission properties of two chairside CAD/CAM lithium disilicate (LD) ceramics (a novel fully crystallized and a traditional pre-crystallized) across varying thicknesses. Materials and Methods: One hundred flat specimens were obtained from precrystallized (e.max CAD,
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Aim: This in vitro study aimed to compare the light-transmission properties of two chairside CAD/CAM lithium disilicate (LD) ceramics (a novel fully crystallized and a traditional pre-crystallized) across varying thicknesses. Materials and Methods: One hundred flat specimens were obtained from precrystallized (e.max CAD, Ivoclar Vivadent, Schaan, Liechtenstein) and fully crystallized (LiSi GC Block; GC, Tokyo, Japan) LD at five different thicknesses (0.5, 0.75, 1.0, 1.50 and 2.0 mm). All specimens were polished with a polishing system for lithium disilicate restorations following recommendations from the manufacturer. Light transmission was evaluated with a radiometer. The statistical analysis between e.max CAD and LiSi GC Block was performed using a Mann–Whitney test for each thickness at a significance level of 0.05 (p < 0.05), followed by a Kruskal–Wallis test to compare the light transmission between the thicknesses of e.max CAD and LiSi GC Block. Results: Light transmittance was significantly affected by ceramic thickness. The 0.5 mm thick specimens exhibited the highest transmittance values compared to all other groups, while a light transmittance of 0.00 was observed in the 2.0 mm thick specimens for both e.max CAD and LiSi GC Block. In the comparison between e.max CAD and LiSi GC Block according to thickness, there was a statistically significant difference exclusively between groups with a thickness of 1.50 mm (p = 0.002). Conclusions: Light transmission for pre- and fully crystallized CAD/CAM lithium disilicate ceramics only showed a statistical difference at the thickness of 1.50 mm (p = 0.002). E.max CAD demonstrated acceptable light transmission up to a thickness of 1.5 mm. Clinical Significance: A thickness of 2 mm for chairside CAD/CAM lithium disilicate ceramics, whether pre-crystallized or fully crystallized, necessitates the use of dual-cure resin luting cement due to reduced light transmission.
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(This article belongs to the Special Issue Characteristics of Dental Ceramics)
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