Journal Description
Water
Water
is a peer-reviewed, open access journal on water science and technology, including the ecology and management of water resources, and is published semimonthly online by MDPI. Water collaborates with the International Conference on Flood Management (ICFM) and Stockholm International Water Institute (SIWI). In addition, the American Institute of Hydrology (AIH), The Polish Limnological Society (PLS) and Japanese Society of Physical Hydrology (JSPH) are affiliated with Water and their members receive a discount on the article processing charges.
- Open Access— free for readers, with article processing charges (APC) paid by authors or their institutions.
- High Visibility: indexed within Scopus, SCIE (Web of Science), Ei Compendex, GEOBASE, GeoRef, PubAg, AGRIS, CAPlus / SciFinder, Inspec, and other databases.
- Journal Rank: JCR - Q2 (Water Resources) / CiteScore - Q1 (Water Science and Technology)
- Rapid Publication: manuscripts are peer-reviewed and a first decision is provided to authors approximately 16.5 days after submission; acceptance to publication is undertaken in 2.9 days (median values for papers published in this journal in the second half of 2023).
- Recognition of Reviewers: reviewers who provide timely, thorough peer-review reports receive vouchers entitling them to a discount on the APC of their next publication in any MDPI journal, in appreciation of the work done.
- Companion journals for Water include: GeoHazards and Hydrobiology.
Impact Factor:
3.4 (2022);
5-Year Impact Factor:
3.5 (2022)
Latest Articles
Cladocera and Geochemical Variables from Core Sediments Show Different Conditions of Hungarian Lakes
Water 2024, 16(9), 1310; https://doi.org/10.3390/w16091310 (registering DOI) - 05 May 2024
Abstract
Studies on the sediments of lakes with varying trophic status are of particular importance when considering changes in the natural environment. In this study, our objective was to examine subfossil remains of Cladocera species and the relationship between the sedimental Cladocera assemblages and
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Studies on the sediments of lakes with varying trophic status are of particular importance when considering changes in the natural environment. In this study, our objective was to examine subfossil remains of Cladocera species and the relationship between the sedimental Cladocera assemblages and geochemical variables during 11 years of sediment records from northern Hungarian lakes. To achieve this, we compared sedimental cladoceran communities and the geochemistry of the sediment layers among lakes. Among the studied lakes, one was an intermittent lake (KMT: the Kis-Morotva Lake) which dried out in 2012 but was subsequently naturally refilled in 2013 by groundwater affected by the high-water level of the River Tisza. The other type consisted of permanent lakes (SZA: the Szabolcs oxbow lake, TI: the Timár Morotva Lake) that never dried out. The results of the beta diversity analysis show that the deposition of Cladocera communities was similar among the sediment layers of lakes, while the abundance differences contributed significantly to replacement. Subsequently, core sediment samples of the three lakes were compared based on the remains of Cladocera communities and geochemical variables using Adonis (PERMANOVA). The core sediment samples indicate variations in Cladocera communities alongside disparities in geochemical variables across the same lakes. In conclusion, the significance of sediment cores containing the remains of the Cladocera community has grown significantly in the reconstruction of historical ecological and climatic changes.
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(This article belongs to the Special Issue Biodiversity of Freshwater Ecosystems: Monitoring and Conservation)
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Open AccessArticle
Advanced Uncertainty Quantification for Flood Inundation Modelling
by
Gordon Aitken, Lindsay Beevers and Mike A. Christie
Water 2024, 16(9), 1309; https://doi.org/10.3390/w16091309 (registering DOI) - 05 May 2024
Abstract
Flood hazards present a significant risk to the UK, with homes, businesses and critical infrastructure exposed to a mixture of fluvial, surface water and coastal flooding. Climate change is expected to influence river flows, changing the frequency and magnitude of future flood events.
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Flood hazards present a significant risk to the UK, with homes, businesses and critical infrastructure exposed to a mixture of fluvial, surface water and coastal flooding. Climate change is expected to influence river flows, changing the frequency and magnitude of future flood events. Flood hazard assessments are used by decision-makers to implement policies and engineering interventions to reduce the impacts of these flood events. Probabilistic flood modelling can explore input and parameter uncertainties in flood models to fully quantify inundation uncertainty. However, probabilistic methods require large computational costs—limiting their application. This paper investigates a range of advanced uncertainty quantification methods (traditional Monte Carlo (FMC), Kriging and multi-fidelity Monte Carlo (MFMC)) to reduce the dichotomy between accuracy and costs. Results suggest that Kriging can reduce computational costs by 99.9% over FMC. The significantly increased efficiency has the potential to improve future policy and engineering decisions, reducing the impacts of future flood events.
Full article
Open AccessArticle
Numerical Analysis of the Stress Shadow Effects in Multistage Hydrofracturing Considering Natural Fracture and Leak-Off Effect
by
Jinxin Song, Qing Qiao, Chao Chen, Jiangtao Zheng and Yongliang Wang
Water 2024, 16(9), 1308; https://doi.org/10.3390/w16091308 (registering DOI) - 04 May 2024
Abstract
As a critical technological approach, multistage fracturing is frequently used to boost gas recovery in compact hydrocarbon reservoirs. Determining an ideal cluster distance that effectively integrates pre-existing natural fractures in the deposit creates a fracture network conducive to gas movement. Fracturing fluid leak-off
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As a critical technological approach, multistage fracturing is frequently used to boost gas recovery in compact hydrocarbon reservoirs. Determining an ideal cluster distance that effectively integrates pre-existing natural fractures in the deposit creates a fracture network conducive to gas movement. Fracturing fluid leak-off also impacts water resources. In our study, we use a versatile finite element–discrete element method that improves the auto-refinement of the grid and the detection of multiple fracture movements to model staged fracturing in naturally fractured reservoirs. This computational model illustrates the interaction between hydraulic fractures and pre-existing fractures and employs the nonlinear Carter leak-off criterion to portray fluid leakage and the impacts of hydromechanical coupling during multistage fracturing. Numerical results show that sequential fracturing exhibits the maximum length in unfractured and naturally fractured models, and the leak-off volume of parallel fracturing is the smallest. Our study proposes an innovative technique for identifying and optimizing the spacing of fracturing clusters in unconventional reservoirs.
Full article
(This article belongs to the Special Issue Thermo-Hydro-Mechanical Coupling in Fractured Porous Media)
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Open AccessArticle
Effects of Different Reclamation Years and Modes on Soil Moisture Transport Pathways and Permeability Characteristics in an Open-Pit Mining Area in Guangxi
by
Song Wang, Lei Gan, Yu Zhang, Zhibo Gao, Zhenhong Luo, Haojie Zhou, Hang Zhang, Hongxia Zhang and Taiqing Huang
Water 2024, 16(9), 1307; https://doi.org/10.3390/w16091307 (registering DOI) - 04 May 2024
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The microstructural characteristics of reclaimed soil in Guangxi’s bauxite mining area play a pivotal role in determining soil reclamation quality, yet they remain poorly understood. To explore the impact of varying reclamation years and modes on pore structure characteristics in this region, we
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The microstructural characteristics of reclaimed soil in Guangxi’s bauxite mining area play a pivotal role in determining soil reclamation quality, yet they remain poorly understood. To explore the impact of varying reclamation years and modes on pore structure characteristics in this region, we selected four reclamation regions: grassland reclamation with 2 years (RG2a), grassland reclamation with 10 years (RG10a), bare ground reclamation with 2 years (RW2a) and bare ground reclamation with 10 years (RW10a). Utilizing X-ray CT technology, we scanned soil columns within a 30 cm depth to analyze pore distributions using Avizo 2020 software combined with ImageJ 1.53c and its plugins. The findings revealed a significant increase in the number of 2D and 3D macropores by 1.09% and 88.89% in RG10a compared to RG2a, as well as 39.01% and 13.33% in RG10a compared to RW10a, respectively. Furthermore, RG10a was observed to be more effective in enhancing the rounding rate of macropores and mesopores, as well as average branch length and density. Additionally, RG10a demonstrated a greater capacity to increase porosity and connectivity while reducing curvature and specific surface area among the three-dimensional parameters. The 3D reconstruction illustrated that RG modes exhibited a more abundant distribution of macropores compared to RW modes and 10a modes showed a higher presence of macropores than 2a modes, which displayed a tilted laminar pattern. Soil moisture movement simulations conducted through Avizo 2020 under various modes indicated that RG modes presented a more extensive capacity for vertical flow, while 10a modes displayed more abundant flow lines and a higher infiltration rate (K) compared to 2a modes. In conclusion, prolonged reclamation years favoring grassland reclamation modes could enhance water and nutrient transport pathways toward traditional agricultural soil.
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Open AccessArticle
From Recharge to Cave to Spring: Transmission of a Flood Pulse through a Complex Karst Conduit Network, Castleton, Derbyshire (UK)
by
John Gunn and Chris Bradley
Water 2024, 16(9), 1306; https://doi.org/10.3390/w16091306 (registering DOI) - 04 May 2024
Abstract
Storm Babet (18–21 October 2023) brought heavy and persistent rain (80–100 mm) to the English Peak District, causing widespread surface and underground flooding. The village of Castleton experienced groundwater flooding from springs that drain a complex mixed allogenic–autogenic karst catchment. Transmission of the
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Storm Babet (18–21 October 2023) brought heavy and persistent rain (80–100 mm) to the English Peak District, causing widespread surface and underground flooding. The village of Castleton experienced groundwater flooding from springs that drain a complex mixed allogenic–autogenic karst catchment. Transmission of the flood pulse was monitored using high-resolution (2 and 4 min intervals) logging of (a) the hydraulic head at five underground locations in the karst conduits and (b) the water depth at three springs and in the surface river fed by the springs. Underground, there were large increases in the hydraulic head (9–35 m), which resulted in two types of flow switching. Firstly, the increased head at the input end of a phreatic (water-filled) conduit system removed an underwater permeability barrier in a relatively low-elevation conduit, resulting in a dramatic increase in flow out of the conduit and a corresponding decrease in flow from a linked higher-elevation conduit that had dominated before the storm. Secondly, the increased head upstream of two conduits with limited hydraulic conductivity allowed water to spill over into conduits that were inactive prior to the storm. As expected, the conduits fed by sinking streams from the allogenic catchment responded rapidly to the recharge, but there was also a rapid response from the autogenic catchment where there are no surface streams and only a small number of dolines. The complex signals measured underground are not apparent from the spring hydrographs.
Full article
(This article belongs to the Section Hydrogeology)
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Open AccessArticle
Applicability of Single-Borehole Dilution Tests in Aquifers with Vertical Flow
by
Maria L. Calvache, Manuel López-Chicano, Angela M. Blanco-Coronas, Beatriz de la Torre and Carlos Duque
Water 2024, 16(9), 1305; https://doi.org/10.3390/w16091305 - 03 May 2024
Abstract
A set of experimental field single-borehole dilution tests were completed in the Motril–Salobreña detrital aquifer (Spain) in a sector with coarse material in four different moments under variable hydrological conditions. The comparative study of the tracer washing, and the temperature profile patterns for
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A set of experimental field single-borehole dilution tests were completed in the Motril–Salobreña detrital aquifer (Spain) in a sector with coarse material in four different moments under variable hydrological conditions. The comparative study of the tracer washing, and the temperature profile patterns for the tests carried out in two wells located hundreds of m from each other, revealed the presence of ascending vertical flows in one of the wells (not detected by other means) that compromises the reliability of the tracer test. The values of both the apparent horizontal velocity and hydraulic conductivity obtained in the affected well were less than half of those estimated in the well not affected by the upward vertical flows. The repetition of the test eight times during different seasons showed that the hydraulic conductivity calculated from the apparent horizontal velocity can vary; therefore, to approximate to a representative hydraulic conductivity value, using this method is recommended to carry out tests under different hydrological conditions and average the results. The difference generated by the changes in conditions for the specific setting of the study area was 25%. Taking this into account, it was considered that an approximation to the more representative value would be an average under variable hydrological conditions, resulting in a horizontal velocity of 6.7 m/d and hydraulic conductivity of 337 m/d. This information is critical for the management of the aquifer as it has strategic resources against droughts that are becoming more frequent in the Mediterranean area.
Full article
(This article belongs to the Section Hydrogeology)
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Catchment-Scale Hydrologic Effectiveness of Residential Rain Gardens: A Case Study in Columbia, Maryland, USA
by
Benjamin J. Daniels and Jon Alan Yeakley
Water 2024, 16(9), 1304; https://doi.org/10.3390/w16091304 - 03 May 2024
Abstract
To mitigate the adverse impacts of urban stormwater on streams, watershed managers are increasingly using low-impact development and green infrastructure (LID-GI) stormwater control measures, such as rain gardens—vegetated depressional areas that collect and infiltrate runoff from rooftops and driveways. Their catchment-scale performance, however,
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To mitigate the adverse impacts of urban stormwater on streams, watershed managers are increasingly using low-impact development and green infrastructure (LID-GI) stormwater control measures, such as rain gardens—vegetated depressional areas that collect and infiltrate runoff from rooftops and driveways. Their catchment-scale performance, however, can vary widely, and few studies have investigated the cumulative performance of residential rain gardens for event runoff control in intermediate-sized (i.e., 1–10 km2) suburban catchments. We modeled three years of continuous rainfall-runoff from a 3.1 km2 catchment in Columbia, MD, USA, using the Storm Water Management Model (SWMM). Various extents of rain garden implementation at residential houses were simulated (i.e., 25%, 50%, 75%, and 100% coverage) to determine the effects on peak flow, runoff volume, and lag time. On average, treating 100% of residential rooftops in the catchment reduced peak flows by 14.3%, reduced runoff volumes by 11.4%, and increased lag times by 3.2% for the 223 rainfall events during the simulation period. Peak flow reductions were greater for smaller storm events (p < 0.01). Our results show that residential rain gardens can significantly improve the runoff response of suburban catchments, and that they represent an effective and relatively low-cost option for urban watershed management and restoration.
Full article
(This article belongs to the Special Issue Optimizing Green Infrastructure Design and Placement for Integrated Urban Watershed Management)
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Developing a Bankruptcy Theory to Resolve Stakeholders’ Conflict over Optimal Water Allocation: The Case of Hirmand Catchment
by
Ali Sardar Shahraki, Vijay P. Singh and Ommolbanin Bazrafshan
Water 2024, 16(9), 1303; https://doi.org/10.3390/w16091303 - 02 May 2024
Abstract
The growing increase in demand for water and the lack of balance between water supply and demand have led to conflicts among the downstream stakeholders of the international Hirmand River. This river is shared between Iran and Afghanistan and is located in the
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The growing increase in demand for water and the lack of balance between water supply and demand have led to conflicts among the downstream stakeholders of the international Hirmand River. This river is shared between Iran and Afghanistan and is located in the southeast of Iran, in the Sistan region. The Vardkhaneh is divided into two branches, Parian and Sistan, and it is the only main source of water in the Sistan region of Iran. The inner part of Hirmand catchment is considered bankrupt concerning its water resources, so there is a need to take the current status and resulting issues into account in order to resolve conflicts. In Hirmand catchment, four different games of bankruptcy theory, namely proportional (Pr), adjusted proportional (AP), constrained equal award (CEA), and constrained equal losses (CEL), were developed as optimization models based on genetic algorithms. For this purpose, the catchment was simulated with 26 scenarios using the WEAP 2022 version software for an average time period. The results of the bankruptcy game modeling showed that water could be effectively allocated to resolve conflicts among stakeholders. It is therefore recommended to use such a model to resolve fights and optimally allocate resources, even in bankrupt catchments.
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(This article belongs to the Section Water Resources Management, Policy and Governance)
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A Combination of UV and Disinfectant for Inactivating Viable but Nonculturable State Pseudomonas aeruginosa: Efficiency and Mechanisms
by
Jinfeng Zhao, Huichao Zhu, Chen Tao, Zhiquan Wang, Ning Deng and Xin Huang
Water 2024, 16(9), 1302; https://doi.org/10.3390/w16091302 - 02 May 2024
Abstract
Conventional disinfection techniques, relying on a single disinfection step, often fail to directly eliminate microorganisms, instead causing them to enter a viable but nonculturable (VBNC) state. However, microorganisms in the VBNC state retain metabolic activity and can reactivate under suitable conditions, representing a
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Conventional disinfection techniques, relying on a single disinfection step, often fail to directly eliminate microorganisms, instead causing them to enter a viable but nonculturable (VBNC) state. However, microorganisms in the VBNC state retain metabolic activity and can reactivate under suitable conditions, representing a “hidden source of contamination” that threatens drinking water safety. This study fundamentally assessed the feasibility of combined disinfection methods by integrating UV254 with disinfectant (NaClO, PAA, and PDS) for inactivating Pseudomonas aeruginosa (P. aeruginosa), an opportunistic pathogen that has been widely detected in water supply systems. The number of culturable cells was determined using the heterotrophic plate counting (HPC) method, and the number of VBNC cells was quantified using our recently developed qPCR approach. Quantitative analyses showed that combined disinfection methods can effectively reduce both culturable and VBNC cells by several orders of magnitude compared to a single disinfection step. Notably, VBNC P. aeruginosa, after 30 min of UV/NaCIO treatment, was below the detection limit (3.191 log CFU/mL) of PMA-qPCR. The reactivation experiment also confirmed that VBNC P. aeruginosa did not reactivate for 16 h after 30 min of UV/NaClO treatment under controlled laboratory conditions. The higher disinfection capacity of combined methods can be attributed to the generation of reactive radicals. This study highlighted combined disinfection as a promising approach for the inactivation of bacteria in the VBNC state, yet further studies are needed before an application can be considered for minimizing VBNC reactivation in city utility water processing or high-risk building water distribution systems.
Full article
(This article belongs to the Special Issue Monitoring and Assessment of Water Quality in Drinking Water Distribution Systems)
Open AccessArticle
Recovery of Elemental Arsenic from Acidic As-Containing Wastewater by a Hypophosphite Reduction Process
by
Qian Li, Shiyu Zhao, Yan Zhang, Yong Li, Xiaoliang Liu and Yongbin Yang
Water 2024, 16(9), 1301; https://doi.org/10.3390/w16091301 - 02 May 2024
Abstract
Biological oxidation is a low-carbon technology for the treatment of As-containing gold ores, but it causes a large amount of acidic As-containing wastewater that is harmful to the environment. This paper proposed a novel, eco-friendly method to treat this wastewater. Thermodynamic analysis, H
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Biological oxidation is a low-carbon technology for the treatment of As-containing gold ores, but it causes a large amount of acidic As-containing wastewater that is harmful to the environment. This paper proposed a novel, eco-friendly method to treat this wastewater. Thermodynamic analysis, H2PO2− reduction, and wastewater recycling tests were conducted. Thermodynamic analysis indicates the feasibility of the reduction of As(V)/As(III) by H2PO2− or H3PO2 to As0 under acidic conditions. Experimental results confirmed the thermodynamic prediction and showed that H2PO2− could efficiently convert the As (i.e., As(V)/As(III)) in the wastewater to high value-added As0. Under the optimal conditions, 99.61% of As precipitated out, and the obtained As0 had a high purity of 98.5%. Kinetic results showed that the reaction order of H2PO2− concentration was 0.6399, and the activation energy of the H2PO2− reduction process was 34.33 kJ/mol, which is indicative of a mixed-controlled process (20–40 kJ/mol). Wastewater recycling results showed that after recovering As, the wastewater could be reused as a bacterial culture medium. Based on the thermodynamic analysis and experimental and analytical results, hypophosphite reduction mechanisms for removing and recovering As from its acidic wastewater were proposed. The results presented in this paper suggest the feasibility of this one-step H2PO2− reduction approach, which may be promising in treating acidic As-containing wastewater.
Full article
(This article belongs to the Section Wastewater Treatment and Reuse)
Open AccessArticle
Improving Irrigation Management of Cotton with Small Unmanned Aerial Vehicle (UAV) in Texas High Plains
by
Avay Risal, Haoyu Niu, Jose Luis Landivar-Scott, Murilo M. Maeda, Craig W. Bednarz, Juan Landivar-Bowles, Nick Duffield, Paxton Payton, Pankaj Pal, Robert J. Lascano, Timothy Goebel and Mahendra Bhandari
Water 2024, 16(9), 1300; https://doi.org/10.3390/w16091300 - 02 May 2024
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The rapid decline in water availability for irrigation on the Texas High Plains (THP) is a significant problem affecting crop production and the viability of a large regional economy worth approximately USD 7 billion annually. This region is the largest continuous cotton-producing area
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The rapid decline in water availability for irrigation on the Texas High Plains (THP) is a significant problem affecting crop production and the viability of a large regional economy worth approximately USD 7 billion annually. This region is the largest continuous cotton-producing area in the United States, and the timely delivery and efficient use of irrigation water are critical to the sustainability and profitability of cotton production in this region. Current irrigation scheduling must be improved to reduce water consumption without compromising crop production. Presently, irrigation scheduling based on reference evapotranspiration (ETo) is limited due to the lack of reliable and readily available in-field weather data and updated crop coefficients. Additionally, in-field variability in crop water demand is often overlooked, leading to lower irrigation efficiency. To address these challenges, we explored the potential use of an unmanned aerial vehicle (UAV)-based crop monitoring system to support irrigation management decisions. This study was conducted in Lubbock, Texas, in 2022, where high temporal and spatial resolution images were acquired using a UAV from a cotton field experiment with four irrigation levels. Soil moisture and canopy temperature sensors were deployed to monitor crop response to irrigation and rainfall. The results indicated a significant effect of water stress on crop growth (revealed by UAV-based canopy cover (CC) measurements), yield, and fiber quality. Strong correlations between multi-temporal CC and lint yield (R2 = 0.68 to 0.88) emphasized a clear trend: rainfed treatments with lower yields exhibited reduced CC, while irrigated plots with higher CC displayed increased yields. Furthermore, irrigated plots produced more mature and uniform fibers. This study also explored various evapotranspiration calculation approaches indicating that site-specific CC measurements obtained from a UAV could significantly reduce irrigation application. A regression model linking evapotranspiration to canopy cover demonstrated promising potential for estimating water demand in crops with an R2 as high as 0.68. The findings highlight the efficacy of UAV-based canopy features in assessing drought effects and managing irrigation water in water-limited production regions like the THP.
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Open AccessArticle
Challenges When Assessing Water-Related Environmental Impacts of Livestock Farming: A Case Study of a Cow Milk Production System in Catalonia
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Marta Ruiz-Colmenero, Ariadna Bàllega, Miquel Andón, Marta Terré, Maria Devant, Assumpció Antón, Ralph K. Rosenbaum, Anna Targa and Montserrat Núñez
Water 2024, 16(9), 1299; https://doi.org/10.3390/w16091299 - 02 May 2024
Abstract
Water availability is a local issue of growing importance in Mediterranean areas where water scarcity linked to climate change and population growth is already leading to increased competition for this resource. This study is aimed at the following: (i) assessing the water-related environmental
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Water availability is a local issue of growing importance in Mediterranean areas where water scarcity linked to climate change and population growth is already leading to increased competition for this resource. This study is aimed at the following: (i) assessing the water-related environmental impacts (water use, freshwater ecotoxicity and eutrophication, marine eutrophication, acidification, human toxicity, and ionizing radiation) along the production chain of cow milk in Catalonia, northeastern Spain; and (ii) addressing the issues encountered (modelling choices, data gaps and inconsistencies) which t can affect the quality of results when performing a water-footprint comprehensive assessment, focusing on water use and associated water scarcity impacts. The scope included the process from the extraction of raw materials up to the distribution of the packaged fat- and protein-corrected milk to the distribution centres of the supermarket chains and markets. Results showed the farm stage to be determinant (contributing to over 60% of the impact), due to the impact of feed production. Impact results were in the range of the European benchmark given by the Product Environmental Footprint Category Rules for dairy products, except for the water scarcity footprint which was one order of magnitude larger than the reference value, due to water scarcity in Spain. Considering compound feed ingredients with a lower water scarcity footprint, and research into slurry treatment for its use as irrigation and cleaning water (without compromising safety and health) could help reduce this impact. Water accounting and traceability along the production chain could support the dairy industry to take responsibility for the consequences of their production choices.
Full article
(This article belongs to the Special Issue Assessment of Water Use in Livestock Production Systems and Supply Chains)
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Open AccessArticle
Films Floating on Water Surface: Coupled Redox Cycling of Iron Species (Fe(III)/Fe(II)) at Soil/Water and Water/Air Interfaces
by
Hong Zhang, Zac Rush, Zoe Penn, Kami Dunn, Sydney Asmus, Carolyn Cooke, Zach Cord, Shawna Coulter and Chance Morris
Water 2024, 16(9), 1298; https://doi.org/10.3390/w16091298 - 02 May 2024
Abstract
Naturally occurring Fe(III) films with rainbow reflection iridescence have been observed floating on the water surface of various spots covered with shallow water (e.g., edges of wetlands and creeks, standing water over soils). This natural phenomenon has become a scenic attraction and stimulated
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Naturally occurring Fe(III) films with rainbow reflection iridescence have been observed floating on the water surface of various spots covered with shallow water (e.g., edges of wetlands and creeks, standing water over soils). This natural phenomenon has become a scenic attraction and stimulated much curiosity. We pursued an experimental inquiry aimed at probing this interesting, curious natural wonder. As the first critical task, floating Fe(III) films were successfully generated in an assessable, controllable setting in our laboratory. This enabled us to establish this phenomenon reproducibly under controlled conditions and characterize the phenomenon over the entire span of the formation and transformation of the Fe(III) films. Our film generation method requires a few things: fresh soil (source for Fe(III) and microbes), glucose (energy source), and water in a container. The floating Fe(III) films as observed in the field occurred in ~1–3 day(s) on the water surface of the inundated soil mixed with the sugar. The Fe(III) films then grew from initial very thin, colorless, somewhat transparent films with rainbow reflection iridescence to colored thicker films and then to orange/orange-red/red crusts over the time. A comprehensive mechanistic picture was formulated to depict the formation of the Fe(III) films. Several sequential processes are operative. First, the Fe(III) (oxides, oxyhydroxides) in the soil is reduced to Fe(II) by the Fe(III)-reducing microbes during their anerobic respiration with Fe(III) as the electron (e−) acceptor after depletion of dissolved O2 in the water as a result of aerobic microbial respiration with O2 as the e− acceptor. The Fe(II), being soluble, then diffuses to the water surface where it is oxidized to Fe(III). Subsequently, the Fe(III) hydrolyzes and various Fe(III) hydrolysis products polymerize to stabilize. A polymeric model was created to account for the Fe(III) film transformation. The Fe(III) films are considered to transform from the dimers and trimers and linear polymers of Fe(OH)3 to Fe(III) polymer sheets (e.g., Fe(OH)3, FeOOH), to 3D Fe(III) polymers, and eventually to Fe2O3 colloid particles. This floating Fe(III) film phenomenon boasts an environmental chemical drama of redox cycling of Fe(III)/Fe(II) at soil/water and water/air interfaces coupled with Fe(II) transport from the inundated soil to the water surface followed by ultimate mineralization of the Fe(III) polymers. Our Fe(III) film generation method can be readily scaled up to supply Fe(III) films of rich varieties in thickness, size, morphology, and structure over the entire span of various stages of their formation and transformation as desired for various uses. This setup offers a platform needed for further controlled studies on the kinetics, mechanism, and process of abiotic and biotic nature involved in the Fe(III) film phenomenon and for exploration of versatile roles of the Fe(III) films as nanofilms in Fe(III)/Fe(II)-surface catalyzed chemical and photochemical reactions involving various natural and synthetic compounds.
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Open AccessArticle
Comprehensive Profiling of Klebsiella in Surface Waters from Northern Portugal: Understanding Patterns in Prevalence, Antibiotic Resistance, and Biofilm Formation
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Sara Araújo, Vanessa Silva, Maria de Lurdes Enes Dapkevicius, José Eduardo Pereira, Ângela Martins, Gilberto Igrejas and Patricia Poeta
Water 2024, 16(9), 1297; https://doi.org/10.3390/w16091297 - 02 May 2024
Abstract
This study investigates the prevalence of resistance and virulence genes in Klebsiella isolates from surface waters in Northern Portugal, within the broader context of freshwater quality challenges in Southern Europe. The aim of this research is to explain how Klebsiella dynamics, antibiotic resistance,
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This study investigates the prevalence of resistance and virulence genes in Klebsiella isolates from surface waters in Northern Portugal, within the broader context of freshwater quality challenges in Southern Europe. The aim of this research is to explain how Klebsiella dynamics, antibiotic resistance, and biofilm formation interact in surface waters. Antimicrobial susceptibility was examined using the Kirby–Bauer disk diffusion method against 11 antibiotics and screening for Extended-Spectrum Beta-Lactamase (ESBL) production using the double-disk synergy. PCR was employed to detect resistance and virulence genes, while biofilm production was assessed using the microplate method. Out of 77 water isolates, 33 Klebsiella (14 Klebsiella spp. and 19 K. pneumoniae strains) were isolated. ESBL production was observed in 36.8% of K. pneumoniae and 28.6% of Klebsiella spp. High resistance rates to blaCTX-U were observed in both. The papC gene was prevalent, signifying potential environmental risks. Biofilm production averaged 81.3% for K. pneumoniae and 86.9% for Klebsiella spp. These findings underscore the intricate interplay between Klebsiella’s dynamics and freshwater quality, with ESBL’s prevalence raising concerns about waterborne dissemination and public health implications. This work supports the need for vigilance of Klebsiella in surface waters in Southern Europe.
Full article
(This article belongs to the Special Issue Freshwater Quality Challenges in Southern Europe under an Increasingly Warmer and Drier Climate Scenario)
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Open AccessArticle
Numerical Study on the Formation Mechanism of Plume Bulge in the Pearl River Estuary under the Influence of River Discharge
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Chenyu Zhao, Nan Wang, Yang Ding, Dehai Song, Junmin Li, Mengqi Li, Lingling Zhou, Hang Yu, Yanyu Chen and Xianwen Bao
Water 2024, 16(9), 1296; https://doi.org/10.3390/w16091296 - 02 May 2024
Abstract
Previous studies have investigated the characteristics and influencing factors of plume bulge in the Pearl River Estuary (PRE) using observations and numerical simulations. However, the understanding of how river discharge affects plume bulge is not consistent, and the response mechanism of plume bulge
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Previous studies have investigated the characteristics and influencing factors of plume bulge in the Pearl River Estuary (PRE) using observations and numerical simulations. However, the understanding of how river discharge affects plume bulge is not consistent, and the response mechanism of plume bulge to changes in river discharge has not been revealed in detail. In this study, a three-dimensional hydrodynamic Finite-Volume Coastal Ocean Model (FVCOM) is constructed, and five experiments were set to characterize the horizontal and vertical distribution of the plume bulge outside the PRE under different river discharge conditions during spring tide. The physical mechanisms of plume bulge generation and its response mechanisms to river discharge were discussed through standardized analysis and momentum diagnostic analysis. The results indicate that the plume bulge is sensitive to changes in river discharge. When the river discharge is relatively low (e.g., less than 11,720 m3/s observed in the dry season), the bulge cannot be formed. Conversely, when the river discharge is relatively high (e.g., exceeding 23,440 m3/s observed in flood season), the bulge is more significant. The plume bulge is formed by the anticyclonic flow resulting from the action of the Coriolis force on the strongly mixed river plume. The bulge remains stable under the combined effects of barotropic force, baroclinic gradient force, and Coriolis force. The reduction of river discharge weakens the mixing of freshwater and seawater, resulting in the reduction of both the volume and momentum of the river plume, and the balance between advective diffusion and Coriolis forces are altered, resulting in the plume, which is originally flushed out from the Lantau Channel, not being able to maintain the anticyclonic structure and instead floating out along the coast of the western side of the PRE, with the disappearance of the plume bulge. Due to the significant influence of plume bulges on the physical and biogeochemical interactions between estuaries and terrestrial environments, studying the physical mechanisms behind the formation of plume bulges is crucial.
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(This article belongs to the Special Issue Coastal Management and Nearshore Hydrodynamics)
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Open AccessArticle
Dual Effect of Microplastics and Cadmium on Stream Litter Decomposition and Invertebrate Feeding Behavior
by
Hualong He, Sulin Cai, Siyuan Chen, Qiang Li, Yunchao Luo, Xiaoyi Zeng, Rumeng Ye, Pengwei Wan and Xingjun Tian
Water 2024, 16(9), 1295; https://doi.org/10.3390/w16091295 - 02 May 2024
Abstract
This study investigates the combined effect of microplastics and cadmium on the decomposition of litter, the structure of fungal communities, and the feeding behavior of invertebrates in an aquatic ecosystem. Through a series of microcosm experiments, we demonstrate that exposure to MPs and
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This study investigates the combined effect of microplastics and cadmium on the decomposition of litter, the structure of fungal communities, and the feeding behavior of invertebrates in an aquatic ecosystem. Through a series of microcosm experiments, we demonstrate that exposure to MPs and Cd significantly reduced the decomposition of leaf litter. Notably, the cumulative impact of combined MP and Cd exposure was found to be greater than their individual effects. During this process, the carbon–nitrogen ratio of the litter increased, while dehydrogenase activity and fungal biomass were inhibited. Additionally, the relative abundance of Ascomycota and Basidiomycota fungi decreased, weakening their role in the decomposition of leaf litter. Conversely, MPs and Cd reduced the relative content of leaf litter lignin, improving its quality as food, thereby leading to an increase in the feeding rate of invertebrates. This dual effect indicates that micropollutants suppress the decomposition of litter by regulating microbial metabolic activity and fungal community structure but promote invertebrate feeding. Our findings provide crucial insights into the adverse effects of MPs and Cd on the structure and diversity of aquatic fungal communities, which could have long-term impacts on the food webs and nutrient cycling progress of aquatic ecosystems.
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(This article belongs to the Section Water Quality and Contamination)
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Open AccessArticle
Analysis of Unsteady Internal Flow and Its Induced Structural Response in a Circulating Water Pump
by
Jinqi Lu, Xueliang Yao, Haixia Zheng, Xiaowei Yan, Houlin Liu and Tianxin Wu
Water 2024, 16(9), 1294; https://doi.org/10.3390/w16091294 - 02 May 2024
Abstract
As critical equipment in nuclear power systems, the stability of circulating water pumps (CWP) directly impacts the efficiency of power plants. To investigate the impact mechanisms of the unsteady flow characteristics and flow-induced forces on the rotation system, numerical simulation methods were employed
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As critical equipment in nuclear power systems, the stability of circulating water pumps (CWP) directly impacts the efficiency of power plants. To investigate the impact mechanisms of the unsteady flow characteristics and flow-induced forces on the rotation system, numerical simulation methods were employed to calculate the internal flow of a volute mixed-flow CWP under different flow rates (0.8Qd, 1.0Qd, 1.2Qd). The flow field results indicate that, under the part-load condition, the flow within the volute is chaotic with high energy losses, while under the over-load condition, there is a significant velocity gradient within the impeller, leading to relatively severe flow losses. Additionally, the rotor–stator interface is a major factor in flow-induced pulsations, and the asymmetric pressure distribution within the volute results in radial force imbalance. The finite element method (FEM) results indicate that the position of maximum stress on the pump shaft is closely related to the ratio of radial and axial force. Increasing the flow rate appropriately has been noted to be advantageous in reducing flow-induced forces and their amplitude, consequently diminishing the forces on the rotation system and improving the long-term operational stability of the CWP.
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(This article belongs to the Section Hydraulics and Hydrodynamics)
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Open AccessCommunication
Modeling of Biofoam Destabilization by Biodefoamers in Poultry Slaughterhouse Wastewater Treatment Activated Sludge
by
Cynthia Dlangamandla, Ncumisa Mpongwana, Seteno K. O. Ntwampe, Moses Basitere and Boredi S. Chidi
Water 2024, 16(9), 1293; https://doi.org/10.3390/w16091293 - 01 May 2024
Abstract
Biofoam formation in wastewater treatment is a challenge globally. Previously, we successfully proposed the use of biodefoamers instead of synthetic defoamers for environmental protection. In this study, we report on biodefoamation modeling using activated sludge organisms. Overall, the rate law model was determined
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Biofoam formation in wastewater treatment is a challenge globally. Previously, we successfully proposed the use of biodefoamers instead of synthetic defoamers for environmental protection. In this study, we report on biodefoamation modeling using activated sludge organisms. Overall, the rate law model was determined to adequately describe foam drainage including collapse while applying biodefoamers. The target industry is the poultry processing industry whereby foam formation during wastewater treatment is an ongoing challenge.
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(This article belongs to the Section Wastewater Treatment and Reuse)
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Mine Wastewater Effect on the Aquatic Diversity and the Ecological Status of the Watercourses in Southern Poland
by
Krzysztof Mitko, Piotr Dydo, Andrzej K. Milewski, Joanna Bok-Badura, Agata Jakóbik-Kolon, Tomasz Krawczyk, Anna Cieplok, Mariola Krodkiewska, Aneta Spyra, Grzegorz Gzyl, Anna Skalny, Beata Kończak, Maria Bałazińska, Paweł Łabaj, Anna Tetłak, Maria Kyriazi and Stavroula Klempetsani
Water 2024, 16(9), 1292; https://doi.org/10.3390/w16091292 - 01 May 2024
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Coal mining activity contributes to energy security and employment occupation, but is associated with environmental deterioration. Coal combustion leads to GHG emissions, while coal mining results in the generation of saline effluents. These effluents are discharged in inland surface waters, applying significant pressure
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Coal mining activity contributes to energy security and employment occupation, but is associated with environmental deterioration. Coal combustion leads to GHG emissions, while coal mining results in the generation of saline effluents. These effluents are discharged in inland surface waters, applying significant pressure on their quality, with a negative impact on aquatic life and the economy of a region. This study includes water samples that were analyzed in order to investigate the organic compounds, heavy metals, and other physicochemical parameters. Biological monitoring was done according to the Water Framework Directive methodology. The results from an aquatic area in Southern Poland, which indirectly receives coal mine effluents, indicate elevated salinity with excessive chlorides, sulfates, and sodium ions. The water quality of another non-polluted aquatic area was also assessed to examine the impact of indirect coal mine wastewater discharge on this area. The high salinity levels hinder the use of river water for drinking, agricultural, or industrial purposes. The results obtained show high pressure on the ecological status of streams and rivers that receive mine effluents, and on the density and diversity of aquatic invertebrates. This pressure is clearly visible in the structure of benthic communities and in invertebrate diversity. It also contributes to the appearance of invasive species and increasing water salinity. Limiting discharges of mine water transporting large loads of saline substances would reduce the negative impact on the quality of river waters and biological life.
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Evaluating the Water Quality of the Keddara Dam (Algeria) Using Water Quality Indices
by
Tosin Sarah Fashagba, Madani Bessedik, Nadia Badr ElSayed, Chérifa Abdelbaki and Navneet Kumar
Water 2024, 16(9), 1291; https://doi.org/10.3390/w16091291 - 01 May 2024
Abstract
Dams are regarded as crucial pieces of structure that store water for irrigation and municipal uses. Given their vital role, the dam’s water quality assessment is considered to be an important criterion and requires constant monitoring. In this research, we attempted to use
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Dams are regarded as crucial pieces of structure that store water for irrigation and municipal uses. Given their vital role, the dam’s water quality assessment is considered to be an important criterion and requires constant monitoring. In this research, we attempted to use two water quality indices (WQIs) methods to assess the water quality of the Keddara Dam, which is located on the Boudouaou River, Algeria, using eleven water quality parameters (temperature, pH, conductivity, turbidity, total suspended solids (TSS), full alkalimetric title (TAC), hydrometric title (TH), nitrite ions (NO2−), nitrate ions (NO3−), ammonium ions (NH4+), and phosphate ions (PO43−)) for data recorded from 29 December 2018 to 3 June 2021. Application of The Canadian Council of Ministers of the Environment (CCME) WQIs and the Weighted Arithmetic Method (WAM) indicated that the Keddara Dam’s water quality parameters were within the WHO’s permissible level, except for the conductivity and turbidity values. The results of the CCME WQI ranged from acceptable (81.92) to excellent (95.08) quality, whereas the WAM WQI ranged from 9.52 to 17.77, indicating excellent quality. This demonstrates that the Keddara Dam is appropriate for agriculture and municipal use. The water quality indices (WQIs) methods are recommended as valuable tools that allow both the public and decision-makers to comprehend and manage the water quality of any aquatic environment by providing flexibility in choosing variables.
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(This article belongs to the Special Issue Water Quality Assessment of River Basins)
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