Journal Description
Materials
Materials
is an international peer-reviewed, open access journal on materials science and engineering published semimonthly online by MDPI. The Portuguese Materials Society (SPM), Spanish Materials Society (SOCIEMAT) and Manufacturing Engineering Society (MES) are affiliated with Materials and their members receive discounts on the article processing charges.
- Open Access— free for readers, with article processing charges (APC) paid by authors or their institutions.
- High Visibility: indexed within Scopus, SCIE (Web of Science), PubMed, PMC, Ei Compendex, CaPlus / SciFinder, Inspec, Astrophysics Data System, and other databases.
- Journal Rank: JCR - Q2 (Metallurgy & Metallurgical Engineering) / CiteScore - Q2 (Condensed Matter Physics)
- Rapid Publication: manuscripts are peer-reviewed and a first decision is provided to authors approximately 13.9 days after submission; acceptance to publication is undertaken in 2.7 days (median values for papers published in this journal in the second half of 2023).
- Recognition of Reviewers: reviewers who provide timely, thorough peer-review reports receive vouchers entitling them to a discount on the APC of their next publication in any MDPI journal, in appreciation of the work done.
- Testimonials: See what our editors and authors say about Materials.
- Companion journals for Materials include: Electronic Materials and Construction Materials.
Impact Factor:
3.4 (2022);
5-Year Impact Factor:
3.8 (2022)
Latest Articles
Experimental Study on Dynamic Mechanical Performance of Post-Fire Concrete Confined by CFRP Sheets
Materials 2024, 17(9), 2076; https://doi.org/10.3390/ma17092076 (registering DOI) - 28 Apr 2024
Abstract
Impact tests on post-fire concrete confined by Carbon Fiber-Reinforced Polymer/Plastic (CFRP) sheets were carried out by using Split Hopkinson Pressure Bar (SHPB) experimental setup in this paper, with emphasis on the effect of exposed temperatures, CFRP layers and impact velocities. Firstly, according to
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Impact tests on post-fire concrete confined by Carbon Fiber-Reinforced Polymer/Plastic (CFRP) sheets were carried out by using Split Hopkinson Pressure Bar (SHPB) experimental setup in this paper, with emphasis on the effect of exposed temperatures, CFRP layers and impact velocities. Firstly, according to the measured stress-strain curves, the effects of experiment parameters on concrete dynamic mechanical performance such as compressive strength, ultimate strain and energy absorption are discussed in details. Additionally, temperature caused a softening effect on the compressive strength of concrete specimens, while CFRP confinement and strain rate play a hardening effect, which can lead to the increase in dynamic compressive strength by 1.8 to 3.6 times compared to static conditions. However, their hardening mechanisms and action stages are extremely different. Finally, nine widely accepted Dynamic Increase Factor (DIF) models considering strain rate effect were summarized, and a simplified model evaluating dynamic compressive strength of post-fire concrete confined by CFRP sheets was proposed, which can provide evidence for engineering emergency repair after fire accidents.
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(This article belongs to the Section Advanced Composites)
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Open AccessArticle
Performance Comparison of Machine Learning Models for Concrete Compressive Strength Prediction
by
Amit Kumar Sah and Yao-Ming Hong
Materials 2024, 17(9), 2075; https://doi.org/10.3390/ma17092075 (registering DOI) - 28 Apr 2024
Abstract
This study explores the prediction of concrete compressive strength using machine learning models, aiming to overcome the time-consuming and complex nature of conventional methods. Four models—an artificial neural network (ANN), a multiple linear regression, a support vector machine, and a regression tree—are employed
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This study explores the prediction of concrete compressive strength using machine learning models, aiming to overcome the time-consuming and complex nature of conventional methods. Four models—an artificial neural network (ANN), a multiple linear regression, a support vector machine, and a regression tree—are employed and compared for performance, using evaluation metrics such as mean absolute deviation, root mean square error, coefficient of correlation, and mean absolute percentage error. After preprocessing 1030 samples, the dataset is split into two subsets: 70% for training and 30% for testing. The ANN model, further divided into training, validation (15%), and testing (15%), outperforms others in accuracy and efficiency. This outcome streamlines compressive strength determination in the construction industry, saving time and simplifying the process.
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(This article belongs to the Section Materials Physics)
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Open AccessArticle
The Influence of Cold Forming and Heat Treatment Processes on the Mechanical and Fracture Properties of AA6016 Aluminum Sheets
by
Baitong Liu, Jiahong Lu, Shiyao Huang, Zuguo Bao, Xilin Li, Zhenfei Zhan and Qing Liu
Materials 2024, 17(9), 2074; https://doi.org/10.3390/ma17092074 (registering DOI) - 28 Apr 2024
Abstract
In order to ascertain the mechanical properties and fracture performance of AA6016 aluminum sheets after cold forming and heat treatment processes, uniaxial tensile tests and fracture tests were conducted under various pre-strain conditions and heat treatment parameters. The experimental outcomes demonstrated that pre-strain
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In order to ascertain the mechanical properties and fracture performance of AA6016 aluminum sheets after cold forming and heat treatment processes, uniaxial tensile tests and fracture tests were conducted under various pre-strain conditions and heat treatment parameters. The experimental outcomes demonstrated that pre-strain and heat treatment had significant impacts on both stress–strain curves and fracture properties. Pre-strain plays a predominant role in influencing the mechanical and fracture properties. The behavior of precipitation hardening under different pre-strains was investigated using Differential Scanning Calorimetry (DSC). The results indicated that pre-strain accelerates the precipitation of the β″ strengthening phase, but excessive pre-strain can inhibit the heat treatment strengthening effect. To consider the influences of pre-strain and heat treatment, a constitutive model, as well as a predictive model for load–displacement curves, was established using a backpropagation (BP) neural network. An analysis of the number of hidden layers and neuron nodes in the network revealed that the accuracy of the model does not necessarily improve with an increase in the number of hidden layers and neuron nodes, and an excessive number might actually decrease the efficiency of the machine learning process.
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(This article belongs to the Section Metals and Alloys)
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Open AccessArticle
Inside the Borate Anomaly: Leveraging a Predictive Modelling Approach to Navigate Complex Composition–Structure–Property Relationships in Oxyhalide Borate Glasses
by
Brenna Kettlewell and Daniel Boyd
Materials 2024, 17(9), 2073; https://doi.org/10.3390/ma17092073 (registering DOI) - 28 Apr 2024
Abstract
This study employs a systematic and predictive modelling approach to investigate the structure and properties of multi-component borate glasses. In particular, this work is focused on understanding the individual and interaction effects of multiple constituents on several material properties. By leveraging advanced modeling
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This study employs a systematic and predictive modelling approach to investigate the structure and properties of multi-component borate glasses. In particular, this work is focused on understanding the individual and interaction effects of multiple constituents on several material properties. By leveraging advanced modeling techniques, this work examines how the inclusion and variation of B2O3, CaF2, TiO2, ZnO, and Na2CO3 influence the glass network, with particular attention to modifier fractions ≥ 30 mol%. This research addresses the gap in knowledge regarding the complex behavior of borate glasses in this high modifier fraction range, known as the borate anomaly, where prediction of glass structure and properties becomes particularly challenging. The use of a design of mixtures (DoM) approach facilitated the generation of polynomial equations indicating the influence of mixture components on various responses, enabling the prediction and optimization of glass properties over broad compositional ranges despite being within the anomalous region. This methodical approach not only advances our understanding of borate glass systems but also underscores the importance of predictive modelling in the accelerated design and development of novel glass materials for diverse applications.
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(This article belongs to the Special Issue Development of Boron-Based Materials)
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Open AccessArticle
Photovoltaic Effect of La and Mn Co-Doped BiFeO3 Heterostructure with Charge Transport Layers
by
Jiwei Lv and Huanpo Ning
Materials 2024, 17(9), 2072; https://doi.org/10.3390/ma17092072 (registering DOI) - 28 Apr 2024
Abstract
Bismuth ferrite BiFeO3 (BFO)-based ferroelectrics have great potential as inorganic perovskite-like oxides for future solar cells applications due to their unique physical properties. In this work, La and Mn co-doped BFO thin films with compositions Bi0.9La0.1(Fe1−xMn
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Bismuth ferrite BiFeO3 (BFO)-based ferroelectrics have great potential as inorganic perovskite-like oxides for future solar cells applications due to their unique physical properties. In this work, La and Mn co-doped BFO thin films with compositions Bi0.9La0.1(Fe1−xMnx)O3 (x = 0, 0.05, 0.1, 0.15) (denoted as BLF, BLFM5, BLFM10, BLFM15, respectively) were prepared via a sol–gel technique on indium tin oxide (ITO) glass. All the films are monophasic, showing good crystallinity. The optical bandgap Eg was found to decrease monotonously with an increase in the Mn doping amount. Compared with other compositions, the BLFM5 sample exhibits a better crystallinity and less oxygen vacancies as indicated by XRD and XPS measurements, thereby achieving a better J–V performance. Based on BLFM5 as the light absorbing layer, the ITO/ZnO/BLFM5/Pt and ITO/ZnO/BLFM5/NiO/Pt heterostructure devices were designed and characterized. It was found that the introduction of the ZnO layer increases both the open circuit voltage (Voc) and the short circuit current density (Jsc) with Voc = 90.2 mV and Jsc = 6.90 μA/cm2 for the Pt/ BLFM5/ZnO/ITO device. However, the insertion of the NiO layer reduces both Voc and Jsc, which is attributed to the weakened built-in electric field at the NiO/BLFM5 interface.
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(This article belongs to the Special Issue Electrical and Optical Properties of Metal Oxide Thin Films)
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Open AccessArticle
Corrosion Resistance of Fe-Based Amorphous Films Prepared by the Radio Frequency Magnetron Sputter Method
by
Tai-Nan Lin, Pin-Hsun Liao, Cheng-Chin Wang, Hung-Bin Lee and Leu-Wen Tsay
Materials 2024, 17(9), 2071; https://doi.org/10.3390/ma17092071 (registering DOI) - 28 Apr 2024
Abstract
Amorphous thin films can be applied to increase the anti-corrosion ability of critical components. Atomized FeCrNiMoCSiB powders were hot-pressed into a disc target for R. F. magnetron sputtering on a 316L substrate to upgrade its corrosion resistance. The XRD spectrum confirmed that the
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Amorphous thin films can be applied to increase the anti-corrosion ability of critical components. Atomized FeCrNiMoCSiB powders were hot-pressed into a disc target for R. F. magnetron sputtering on a 316L substrate to upgrade its corrosion resistance. The XRD spectrum confirmed that the film deposited by R. F. magnetron sputtering was amorphous. The corrosion resistance of the amorphous film was evaluated in a 1 M HCl solution with potentiodynamic polarization tests, and the results were contrasted with those of a high-velocity oxy-fuel (HVOF) coating and 316L, IN 600, and C 276 alloys. The results indicated that the film hardness and elastic modulus, as measured using a nanoindenter, were 11.1 and 182 GPa, respectively. The principal stresses in two normal directions of the amorphous film were about 60 MPa and in tension. The corrosion resistance of the amorphous film was much greater than that of the other samples, which showed a broad passivation region, even in a 1 M HCl solution. Although the amorphous film showed high corrosion resistance, the original pinholes in the film were weak sites to initiate corrosion pits. After polarization tests, large, deep trenches were seen in the corroded 316L substrate; numerous fine patches in the IN 600 alloy and grain boundary corrosion in the C276 alloy were observed.
Full article
(This article belongs to the Special Issue Obtaining and Characterization of New Materials, Volume IV)
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Open AccessArticle
Seismic Damage and Behavior Assessment of Drift-Hardening Concrete Walls Reinforced by LBUHS Bars
by
Jiayu Che, Bunka Son and Yuping Sun
Materials 2024, 17(9), 2070; https://doi.org/10.3390/ma17092070 (registering DOI) - 28 Apr 2024
Abstract
This paper experimentally and analytically investigated the damage and seismic behavior of concrete walls reinforced by low-bond ultra-high-strength (LBUHS) bars. To this end, four half-scale rectangular concrete walls were fabricated and tested under reversed cyclic loading and constant axial compression. The test variables
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This paper experimentally and analytically investigated the damage and seismic behavior of concrete walls reinforced by low-bond ultra-high-strength (LBUHS) bars. To this end, four half-scale rectangular concrete walls were fabricated and tested under reversed cyclic loading and constant axial compression. The test variables were the shear span ratio and the axial load ratio. Based on the test results, the propagation of cracks on the wall surface, the maximum strain capacity of concrete, the hysteresis loops and envelope curves, the residual drifts, and the strain distributions of LBUHS rebars were presented and discussed. The experimental results showed that all the test walls could exhibit drift-hardening capability until at least a 2.0% drift ratio if LBUHS rebars were anchored by nuts at their ends. The test results also indicated that the maximum strain capacity of concrete was above 0.86%, much larger than the currently recommended 0.4%. After unloading from the transient drift ratios of 2.0% and 2.5% for the walls with shear span ratios of 1.5 and 2.0, respectively, the measured residual drift ratios were controlled below 0.4%, which is less than the critical drift ratio (0.5%) having 98% repairable probability recommended in the FEMA document (P-58) for general concrete structures. Furthermore, a numerical method was presented to evaluate the cyclic response of the test walls, and a comparison between the experimental and the calculated results verified the reliability and accuracy of the proposed numerical method.
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(This article belongs to the Collection Concrete and Building Materials)
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Open AccessArticle
Gradient Variation and Correlation Analysis of Physical and Mechanical Properties of Moso Bamboo (Phyllostachys edulis)
by
Tian Jiang, Xinyu Feng, Zexuan Xia, Shuotong Deng and Xuehua Wang
Materials 2024, 17(9), 2069; https://doi.org/10.3390/ma17092069 (registering DOI) - 28 Apr 2024
Abstract
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This study aimed to investigate the gradient properties of bamboo at the microscopic level and provide a basis for improving the utilization rate of bamboo. Using moso bamboo (Phyllostachys edulis (Carrière) J. Houz.) as a research subject, the variation of vascular bundle
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This study aimed to investigate the gradient properties of bamboo at the microscopic level and provide a basis for improving the utilization rate of bamboo. Using moso bamboo (Phyllostachys edulis (Carrière) J. Houz.) as a research subject, the variation of vascular bundle area percentage, chemical content, relative crystallinity (CR), mechanical properties of different bamboo slivers, and correlation between those parameters were analyzed. From the bamboo green layer (BGL) to the bamboo yellow layer (BYL), the distribution of vascular bundles changed from dense to sparse. Cellulose and lignin mass content decreased gently, and hemicellulose mass content showed gradual increases. The CR showed an order of bamboo middle layer (BML) > BGL > BYL. The tensile modulus of elasticity, tensile strength, bending modulus of elasticity, and bending strength decreased from BGL to BYL. The order of influence degree on mechanical properties of moso bamboo was vascular bundle area, hemicellulose content, lignin mass content, density, and CR, and these factors correlated with mechanical properties at a significant level (p < 0.05). Vascular bundle area had a decisive effect on the mechanical properties of bamboo. The vascular bundle area and density were linearly correlated with mechanical properties, while the lignin mass content and CR were curve-linearly correlated with mechanical properties.
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Open AccessArticle
Study on the Effect of Microstructure and Inclusions on Corrosion Resistance of Low-N 25Cr-Type Duplex Stainless Steel via Additive Manufacturing
by
Yang Gu, Jiesheng Lv, Jianguo He, Zhigang Song, Changjun Wang, Han Feng and Xiaohan Wu
Materials 2024, 17(9), 2068; https://doi.org/10.3390/ma17092068 (registering DOI) - 28 Apr 2024
Abstract
Duplex stainless steels are widely used in many fields due to their excellent corrosion resistance and mechanical properties. However, it is a challenge to achieve duplex microstructure and excellent properties through additive manufacturing. In this work, a 0.09% N 25Cr-type duplex stainless steel
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Duplex stainless steels are widely used in many fields due to their excellent corrosion resistance and mechanical properties. However, it is a challenge to achieve duplex microstructure and excellent properties through additive manufacturing. In this work, a 0.09% N 25Cr-type duplex stainless steel was prepared by additive manufacturing (AM) and heat treatment, and its corrosion resistance was investigated. The results show that, compared with S32750 duplex stainless steel prepared by a conventional process, the combination value of film resistance and charge transfer resistance of AM duplex stainless steel was increased by 3.2–5.5 times and the pitting potential was increased by more than 100 mV. The disappearance of residual thermal stress and the reasonable distribution of Cr and N elements in the two phases are the reasons for the improvement of the corrosion resistance of AM duplex stainless steel after heat treatment. In addition, the extremely high purity of AM duplex stainless steel with no visible inclusions resulted in a higher corrosion resistance exhibited at lower pitting-resistance-equivalent number values.
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(This article belongs to the Special Issue Additive Manufacturing of Alloys and Composites)
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Open AccessReview
The Impurity Removal and Comprehensive Utilization of Phosphogypsum: A Review
by
Qingjun Guan, Zhuang Wang, Fujia Zhou, Weijian Yu, Zhigang Yin, Zhenyue Zhang, Ru’an Chi and Juncheng Zhou
Materials 2024, 17(9), 2067; https://doi.org/10.3390/ma17092067 (registering DOI) - 28 Apr 2024
Abstract
Phosphogypsum (PG), a byproduct during the phosphoric acid production process, also known as the wet process, contains complex and diverse impurities, resulting in low utilization and considerable accumulation. This leads to a massive waste of land resources and a series of environmental pollution
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Phosphogypsum (PG), a byproduct during the phosphoric acid production process, also known as the wet process, contains complex and diverse impurities, resulting in low utilization and considerable accumulation. This leads to a massive waste of land resources and a series of environmental pollution problems. Given the current urgent ecological and environmental situation, developing impurity removal processes with low energy consumption and high efficiency, exploring valuable resource recovery, preparing high value-added PG products, and broadening the comprehensive utilization ways of PG are significant strategies to promote the sustainable consumption of PG and sustainable development of the phosphorus chemical industry. This review comprehensively summarizes the advantages and disadvantages of existing PG impurity removal and utilization technologies and probes into the future development direction, which provides references and ideas for subsequent PG research.
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(This article belongs to the Section Construction and Building Materials)
Open AccessReview
A Review on the Carbonation of Steel Slag: Properties, Mechanism, and Application
by
Shuping Wang, Mingda Wang, Fang Liu, Qiang Song, Yu Deng, Wenhao Ye, Jun Ni, Xinzhong Si and Chong Wang
Materials 2024, 17(9), 2066; https://doi.org/10.3390/ma17092066 (registering DOI) - 28 Apr 2024
Abstract
Steel slag is a by-product of the steel industry and usually contains a high amount of f-CaO and f-MgO, which will result in serious soundness problems once used as a binding material and/or aggregates. To relieve this negative effect, carbonation treatment was believed
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Steel slag is a by-product of the steel industry and usually contains a high amount of f-CaO and f-MgO, which will result in serious soundness problems once used as a binding material and/or aggregates. To relieve this negative effect, carbonation treatment was believed to be one of the available and reliable methods. By carbonation treatment of steel slag, the phases of f-CaO and f-MgO can be effectively transformed into CaCO3 and MgCO3, respectively. This will not only reduce the expansive risk of steel slag to improve the utilization of steel slag further but also capture and store CO2 due to the mineralization process to reduce carbon emissions. In this study, based on the physical and chemical properties of steel slag, the carbonation mechanism, factors affecting the carbonation process, and the application of carbonated steel slag were reviewed. Eventually, the research challenge was also discussed.
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(This article belongs to the Special Issue CO2 Mineralization of Calcium Silicates Cements)
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Open AccessEditorial
Advanced Machining Technology for Modern Engineering Materials
by
Panagiotis Karmiris-Obratanski, Muthuramalingam Thangaraj, Beata Leszczyńska-Madej and Angelos P. Markopoulos
Materials 2024, 17(9), 2064; https://doi.org/10.3390/ma17092064 (registering DOI) - 28 Apr 2024
Abstract
Advances in material science have indeed revolutionized engineering, bringing forth a suite of new materials with remarkable properties [...]
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(This article belongs to the Special Issue Advanced Machining Technology for Modern Engineering Materials)
Open AccessArticle
Investigation of the Penetration Performance of the Radial Forging Process for Wrought Aluminium Alloy
by
Yongfei Wang, Linhua Xiong, Dongxiao Feng, Shengdun Zhao and Yi Guo
Materials 2024, 17(9), 2065; https://doi.org/10.3390/ma17092065 (registering DOI) - 27 Apr 2024
Abstract
With the wide application potential of wrought aluminium alloy in aerospace, automobile and electronic products, high-quality aluminium bars prepared by the radial forging (RF) process have received extensive attention. Penetration performance refers to the depth of radial plastic deformation of forgings, which is
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With the wide application potential of wrought aluminium alloy in aerospace, automobile and electronic products, high-quality aluminium bars prepared by the radial forging (RF) process have received extensive attention. Penetration performance refers to the depth of radial plastic deformation of forgings, which is the key factor in determining the quality of forging. In this work, the penetration performance of the radial forging process for 6063 wrought aluminium bars is investigated by simulation using FORGE software. The minimum reduction amount of the hammer is calculated based on the forging penetration theory of forging. The influence of process parameters including forging ratio (FR) and billet temperature on the effective stress and hammer load in the RF process are investigated. The RF-deformed billet is then produced with the optimal process parameters obtained from the simulation results. The average grain size of aluminium alloy semi-solid spherical material is used to evaluate the forging penetration. Simulation results showed that the effective strain at the edge and the centre of the RF-deformed billet gradually increases, but the increasing speed of the effective strain at the edge becomes low. The hammer load first decreases quickly and then gradually maintains stability by increasing the FR. It is found that low billet temperature and high FR should be selected as appropriate process parameters under the allowable tonnage range of RF equipment. Under an isothermal temperature of 630 °C and a sustaining time of 10 min, the difference in the average grain dimension between the edge and the centre positions of the starting extruded blank is 186.43 μm, while the difference in the average grain dimension between the edge and the centre positions of the RF-deformed blank is 15.09 μm. The improvement ratio of penetration performance for the RF-deformed blank is obtained as 91.19%.
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(This article belongs to the Special Issue Mechanical Performance and Microstructural Characterization of Light Alloys (Volume II))
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Open AccessArticle
Methodology of Chip Temperature Measurement and Safety Machining Assessment in Dry Rough Milling of Magnesium Alloys Using Different Helix Angle Tools
by
Ireneusz Zagórski, Piotr Zgórniak, Witold Habrat, José Machado and Stanisław Legutko
Materials 2024, 17(9), 2063; https://doi.org/10.3390/ma17092063 (registering DOI) - 27 Apr 2024
Abstract
This paper presents the methodology of measuring chip temperature in the cutting zone in the rough milling of magnesium alloys. Infrared measurements are taken to determine the effect of variable cutting speed, feed per tooth, and depth of cut on the maximum temperature
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This paper presents the methodology of measuring chip temperature in the cutting zone in the rough milling of magnesium alloys. Infrared measurements are taken to determine the effect of variable cutting speed, feed per tooth, and depth of cut on the maximum temperature of chips. Thermal images of chip temperature for a generated collective frame and corresponding histograms are presented. Chip temperatures are presented in numerical terms as median and average values; maximum and minimum values; range; and standard deviation. Box plots are also shown for selected machining conditions. The problems arising during signal recording with a mean emissivity coefficient ε = 0.13, a value which is dedicated during machining magnesium alloys, are discussed in detail. Chip temperatures obtained in the tests do not exceed approx. 420 °C. Therefore, the dry rough milling process carried out with carbide tools with different blade geometries can be considered safe for a wide range of machining parameters. The proposed methodology of chip temperature measurement and result processing is a new and effective approach to safety assessment in the dry milling of magnesium alloys.
Full article
(This article belongs to the Section Manufacturing Processes and Systems)
Open AccessArticle
First-Principles Study of Adsorption of CH4 on a Fluorinated Model NiF2 Surface
by
Tilen Lindič and Beate Paulus
Materials 2024, 17(9), 2062; https://doi.org/10.3390/ma17092062 (registering DOI) - 27 Apr 2024
Abstract
Electrochemical fluorination on nickel anodes, also known as the Simons’ process, is an important fluorination method used on an industrial scale. Despite its success, the mechanism is still under debate. One of the proposed mechanisms involves higher valent nickel species formed on an
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Electrochemical fluorination on nickel anodes, also known as the Simons’ process, is an important fluorination method used on an industrial scale. Despite its success, the mechanism is still under debate. One of the proposed mechanisms involves higher valent nickel species formed on an anode acting as effective fluorinating agents. Here we report the first attempt to study fluorination by means of first principles investigation. We have identified a possible surface model from the simplest binary nickel fluoride (NiF2). A twice oxidized NiF2(F2) (001) surface exhibits higher valent nickel centers and a fluorination source that can be best characterized as an [F2]- like unit, readily available to aid fluorination. We have studied the adsorption of CH4 and the co-adsorption of CH4 and HF on this surface by means of periodic density functional theory. By the adsorption of CH4, we found two main outcomes on the surface. Unreactive physisorption of CH4 and dissociative chemisorption resulting in the formation of CH3F and HF. The co-adsorption with the HF gave rise to four main outcomes, namely the formation of CH3F, CH2F2, CH3 radical, and also physisorbed CH4.
Full article
(This article belongs to the Special Issue The 15th Anniversary of Materials—Recent Advances in Catalytic Materials)
Open AccessArticle
The Effect of Laser Remelting during SLM on Microstructure and Mechanical Properties of CoCrFeNiNb0.25
by
Zhiyuan Yang, Chan Guo, Tao Sun, Jinpeng Hu, Xiaomei Feng and Yifu Shen
Materials 2024, 17(9), 2061; https://doi.org/10.3390/ma17092061 (registering DOI) - 27 Apr 2024
Abstract
A sub-eutectic high-entropy alloy composed of CoCrFeNiNb0.25 was prepared using a combination of mechanical powder mixing and selective laser melting (SLM). The mechanical properties of the alloy were enhanced by employing an interlayer laser remelting process. This study demonstrates the feasibility of
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A sub-eutectic high-entropy alloy composed of CoCrFeNiNb0.25 was prepared using a combination of mechanical powder mixing and selective laser melting (SLM). The mechanical properties of the alloy were enhanced by employing an interlayer laser remelting process. This study demonstrates the feasibility of using mechanical mixing and SLM to form an CoCrFeNiNb0.25 alloy. The interlayer laser remelting process can effectively promote the melting of Nb particles introduced by mechanical mixing, release the stresses near the unfused Nb particles, and reduce their degradation of the specimen properties. The results indicate that the CoCrFeNiNb0.25 alloy, prepared using the interlayer laser remelting process, had an average microhardness of 376 HV, a tensile strength of 974 MPa, and an elongation at break of 10.51%. This process offers a viable approach for rapidly adjusting the composition of high-entropy alloys for SLM forming.
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Open AccessArticle
Influence of Pulsed Interference Laser Heating on Crystallisation of Amorphous Fe77Cu1Si13B9 Ribbons
by
Agnieszka Radziszewska and Olaf Czyż
Materials 2024, 17(9), 2060; https://doi.org/10.3390/ma17092060 (registering DOI) - 27 Apr 2024
Abstract
Amorphous Fe77Cu1Si13B9 ribbons were treated with pulsed laser interference heating (PLIH). The research results will significantly contribute to a better understanding of the impact of PLIH on crystallisation and magnetic properties in precisely defined micro-areas of
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Amorphous Fe77Cu1Si13B9 ribbons were treated with pulsed laser interference heating (PLIH). The research results will significantly contribute to a better understanding of the impact of PLIH on crystallisation and magnetic properties in precisely defined micro-areas of Fe77Cu1Si13B9 (FeCuSiB) ribbons, which has not yet been described in the literature. It was confirmed here that the use of the laser heating process allowed for the achievement of two-dimensional crystallised micro-areas, periodically distributed (at a distance of 17 µm) on the surface of the amorphous ribbons. The correlation between structural changes (SEM, TEM, HRTEM) and the distribution of magnetic field lines of heated amorphous Fe77Cu1Si13B9 ribbons is presented. Particular attention is paid to structural changes in micro-areas where, by controlling the laser interference heating process, the partial crystallisation of amorphous alloys and the formation of clusters or single nanocrystallites (α-Fe(Si)) embedded in an amorphous matrix occur. The addition of copper to the FeSiB alloy promoted the inhibition of grain growth. Electron holography of micro-areas confirmed shifts in the magnetic field lines in the areas of nanocrystallites, the presence of which in the structure caused the magnetisation of the surrounding amorphous matrix.
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(This article belongs to the Section Metals and Alloys)
Open AccessTechnical Note
Exploring the Potential of a Novel Iodine-Based Material as an Alternative Contrast Agent in X-ray Imaging Studies
by
Kristina Bliznakova, Iliyan Kolev, Nikolay Dukov, Tanya Dimova and Zhivko Bliznakov
Materials 2024, 17(9), 2059; https://doi.org/10.3390/ma17092059 (registering DOI) - 27 Apr 2024
Abstract
Background: Contrast-enhanced mammography is one of the new emerging imaging techniques used for detecting breast tissue lesions. Optimization of imaging protocols and reconstruction techniques for this modality, however, requires the involvement of physical phantoms. Their development is related to the use of radiocontrast
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Background: Contrast-enhanced mammography is one of the new emerging imaging techniques used for detecting breast tissue lesions. Optimization of imaging protocols and reconstruction techniques for this modality, however, requires the involvement of physical phantoms. Their development is related to the use of radiocontrast agents. This study assesses the X-ray properties of a novel contrast material in clinical settings. This material is intended for experimental use with physical phantoms, offering an alternative to commonly available radiocontrast agents. Materials and Methods: The water-soluble sodium salt of the newly synthesized diiodine-substituted natural eudesmic acid, Sodium 2,6-DiIodo-3,4,5-TriMethoxyBenzoate [NaDITMB], has been investigated with respect to one of the most commonly applied radiocontrast medium in medical practice—Omnipaque®. For this purpose, simulation and experimental studies were carried out with a computational phantom and a physical counterpart, respectively. Synthetic and experimental X-ray images were subsequently produced under varying beam kilovoltage peaks (kVps), and the proposed contrast material was evaluated. Results and Discussion: Simulation results revealed equivalent absorptions between the two simulated radiocontrast agents. Experimental findings supported these simulations, showing a maximum deviation of 3.7% between the image gray values of contrast materials for NaDITMB and Omnipaque solutions for a 46 kVp X-ray beam. Higher kVp X-ray beams show even smaller deviations in the mean grey values of the imaged contrast agents, with the NaDITMB solution demonstrating less than a 2% deviation compared to Omnipaque. Conclusion: The proposed contrast agent is a suitable candidate for use in experimental work related to contrast-enhanced imaging by utilizing phantoms. It boasts the advantages of easy synthesis and is recognized for its safety, ensuring a secure environment for both the experimenter and the environment.
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(This article belongs to the Special Issue Advanced Biomaterials for Medical Applications (2nd Edition))
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Open AccessEditorial
Characterization, Applications and New Technologies of Civil Engineering Materials and Structures
by
Wensheng Wang, Qinglin Guo and Jue Li
Materials 2024, 17(9), 2058; https://doi.org/10.3390/ma17092058 (registering DOI) - 27 Apr 2024
Abstract
With the continuous development of large-scale maintenance of infrastructure, accurate, reasonable, and efficient mechanical behavior evaluation and performance prediction of civil materials and structures have become the keys to improving service durability and intelligent maintenance management for infrastructure [...]
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(This article belongs to the Special Issue Characterization, Applications and New Technologies of Civil Engineering Materials and Structures)
Open AccessReview
A State of the Art on Cryogenic Cooling and Its Applications in the Machining of Difficult-to-Machine Alloys
by
Mehmet Erdi Korkmaz and Munish Kumar Gupta
Materials 2024, 17(9), 2057; https://doi.org/10.3390/ma17092057 (registering DOI) - 27 Apr 2024
Abstract
Cryogenic cooling has gathered significant attention in the manufacturing industry. There are inherent difficulties in machining materials that are difficult to machine because of high levels of hardness, abrasiveness, and heat conductivity. Increased tool wear, diminished surface finish, and reduced machining efficiency are
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Cryogenic cooling has gathered significant attention in the manufacturing industry. There are inherent difficulties in machining materials that are difficult to machine because of high levels of hardness, abrasiveness, and heat conductivity. Increased tool wear, diminished surface finish, and reduced machining efficiency are the results of these problems, and traditional cooling solutions are insufficient to resolve them. The application of cryogenic cooling involves the use of extremely low temperatures, typically achieved by employing liquid nitrogen or other cryogenic fluids. This study reviews the current state of cryogenic cooling technology and its use in machining difficult-to-machine materials. In addition, this review encompasses a thorough examination of cryogenic cooling techniques, including their principles, mechanisms, and effects on machining performance. The recent literature was used to discuss difficult-to-machine materials and their machining properties. The role of cryogenic cooling in machining difficult materials was then discussed. Finally, the latest technologies and methods involved in cryogenic cooling condition were discussed in detail. The outcome demonstrated that the exploration of cryogenic cooling methods has gained prominence in the manufacturing industry due to their potential to address challenges associated with the machining of exotic alloys.
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(This article belongs to the Special Issue Advanced Machining Technology for Modern Engineering Materials (2nd Edition))
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